Polymer Networks: Principles of Their Formation, Structure and Properties
Springer, 1998 - Science - 343 pages
Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated.
Results 1-3 of 49
Thus, the slopes in Figure 2.10 decrease as v, or the combined molar masses of
the reactants increases. In addition, Table 2. 1 shows that analysis of the slopes
gives values of b which decrease as v^v (the fraction of the chain of v bonds ...
This decrease is primarily due to the formation of cycles. Many of the pendant
double bonds become entrapped in the internally crosslinked structure. The
decrease in reactivity can also be assisted by thermodynamic excluded volume.
As covalent bonds are broken, a decrease in Tg is usually observed. For
example, an epoxy novolac cured with an aromatic diamine (4,4'-
diaminodiphenylsulfone, DDS) showed a maximum glass transition temperature,
Tmax = 215°C at a ...
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Nonlinear polymerization gelation and network formation
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