Polymer Networks: Principles of Their Formation, Structure and PropertiesR.F. Stepto Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated. |
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Page 7
... endlinking non - linear polymerizations were employed to produce so - called model networks , with molecular struc- tures better defined than those of traditional elastomers ( see [ 15 ] ) . From the mid - 1970s , the classical ...
... endlinking non - linear polymerizations were employed to produce so - called model networks , with molecular struc- tures better defined than those of traditional elastomers ( see [ 15 ] ) . From the mid - 1970s , the classical ...
Page 14
... endlinking ' ( polymerization ) . Endlinking may be contrasted with crosslinking , referring to reactions link- ing together existing , primary polymer chains to form branched molecules and eventually networks . Such processes are ...
... endlinking ' ( polymerization ) . Endlinking may be contrasted with crosslinking , referring to reactions link- ing together existing , primary polymer chains to form branched molecules and eventually networks . Such processes are ...
Page 217
... endlinking ( cf. Chapter 2 ) If networks are formed by endlinking functionally terminated chains instead of haphazardly joining chain segments at random , then the nature of this very specific chemical reaction provides the desired ...
... endlinking ( cf. Chapter 2 ) If networks are formed by endlinking functionally terminated chains instead of haphazardly joining chain segments at random , then the nature of this very specific chemical reaction provides the desired ...
Contents
Contents | 1 |
Nonlinear polymerization gelation and network formation | 14 |
4 | 40 |
Copyright | |
14 other sections not shown
Common terms and phrases
behaviour block copolymers Chapter Chem chemical components composition concentration constant conversion copolymerization crosslinking CTT diagram cure curve cyclization decrease deformation degree of polymerization dependence distribution Dušek EANCS Eichinger elastomers endlinking entanglements equation equilibrium Erman experimental Flory formed Frisch gel point gelation hard segments hard-segment content Ilavský increase initial injection moulding intramolecular reaction junction points kinetics linear Macosko Macromol Macromolecules mechanical microphase separation modulus molar mass molecular weight molecules monomer mould network chains network formation network materials network structure network-forming occur parameter phase separation Phys polymer networks Polymer Sci polyurethane predicted primary chains properties PUr-DETDA RA₂ ratio reactants reacted reactive groups RIM copolymer RIM materials ring structures rubber sample shear modulus shown in Figure soft segments soft-segment spinodal spinodal decomposition Stepto stress-strain Tcure temperature tensile thermodynamic thermosetting triol units values versus viscoelastic viscosity vitrification vitrification region volume fraction