Polymer Networks: Principles of Their Formation, Structure and Properties
Springer, 1998 - Science - 343 pages
Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated.
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The plots in Figure 2.14 illustrate the difficulty of separating the compensating
effects of network imperfections and chain interactions. Topological
entanglements in the MDI-based networks are unlikely because the system has a
low value of ...
The cause of this disagreement is the mutual subnetwork entanglements, which
are neglected in the theory. These entanglements prevent the complete phase
separation of both subnetworks and, therefore, they suppress the long-range ...
According to these theories, a set of internal constraints, including knots and
entanglements, are assumed to be fixed during the formation of the network.
These constraints are conserved under deformation, thus contributing to the
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Nonlinear polymerization gelation and network formation
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