Polymer Networks: Principles of Their Formation, Structure and Properties
Springer, 1998 - Science - 343 pages
Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated.
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However, intramolecular reaction (cyclization) can always proceed if the ring
closure is allowed by chain flexibility, so the first crosslinks formed are almost
exclusively intramolecular. Rings of various sizes are formed, with the smallest
In contrast, bulk-polymerized PU copolymers formed under heterogeneous
reaction conditions that induce macrophase (rather than microphase) separation,
produce materials of low molar mass with coarse morphologies and poor
Principles of Their Formation, Structure and Properties R.F. Stepto. including
CC14 and toluene. In all of these, it is observed that optimum gel characteristics
are observed when the composition is «2 parts of s-PMMA to 1 part of i-PMMA.
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Nonlinear polymerization gelation and network formation
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