Polymer Networks: Principles of Their Formation, Structure and PropertiesR.F. Stepto Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated. |
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Page 142
... kinetics differential equations to introduce both time dependence and unequal reactivities for different pairs of reactants . Assumptions used in the modelling required that homogeneous reaction conditions existed and that all groups ...
... kinetics differential equations to introduce both time dependence and unequal reactivities for different pairs of reactants . Assumptions used in the modelling required that homogeneous reaction conditions existed and that all groups ...
Page 154
... kinetics in fast - reacting RIM systems , linked to a comprehensive characterization of materials properties . Thus ... Kinetics of phase separation and polymerization during RIM Examples of studies on the reaction kinetics and the ...
... kinetics in fast - reacting RIM systems , linked to a comprehensive characterization of materials properties . Thus ... Kinetics of phase separation and polymerization during RIM Examples of studies on the reaction kinetics and the ...
Page 155
... kinetics ( Figure 5.12 ( d ) ) and hydrogen - bonding dynamics ( Figure 5.12 ( c ) ) . The importance of this work ... kinetics of such rapid RIM systems may be monitored using the adiabatic temperature rise ( ATR ) technique . Typical ...
... kinetics ( Figure 5.12 ( d ) ) and hydrogen - bonding dynamics ( Figure 5.12 ( c ) ) . The importance of this work ... kinetics of such rapid RIM systems may be monitored using the adiabatic temperature rise ( ATR ) technique . Typical ...
Contents
Contents | 1 |
Nonlinear polymerization gelation and network formation | 14 |
4 | 40 |
Copyright | |
14 other sections not shown
Common terms and phrases
behaviour block copolymers Chapter Chem chemical components composition concentration constant conversion copolymerization crosslinking CTT diagram cure curve cyclization decrease deformation degree of polymerization dependence distribution Dušek EANCS Eichinger elastomers endlinking entanglements equation equilibrium Erman experimental Flory formed Frisch gel point gelation hard segments hard-segment content Ilavský increase initial injection moulding intramolecular reaction junction points kinetics linear Macosko Macromol Macromolecules mechanical microphase separation modulus molar mass molecular weight molecules monomer mould network chains network formation network materials network structure network-forming occur parameter phase separation Phys polymer networks Polymer Sci polyurethane predicted primary chains properties PUr-DETDA RA₂ ratio reactants reacted reactive groups RIM copolymer RIM materials ring structures rubber sample shear modulus shown in Figure soft segments soft-segment spinodal spinodal decomposition Stepto stress-strain Tcure temperature tensile thermodynamic thermosetting triol units values versus viscoelastic viscosity vitrification vitrification region volume fraction