Polymer Networks: Principles of Their Formation, Structure and PropertiesR.F. Stepto Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated. |
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Results 1-3 of 19
Page 146
... spinodal curve meta- unstable stable two - phase region Composition , Figure 5.7 A generalized phase diagram , in terms of 1 / ( xN ) versus composition for a poly- merizing mixture , showing the coexistence and spinodal curves . The ...
... spinodal curve meta- unstable stable two - phase region Composition , Figure 5.7 A generalized phase diagram , in terms of 1 / ( xN ) versus composition for a poly- merizing mixture , showing the coexistence and spinodal curves . The ...
Page 147
... spinodal curve III . No phase separation occurs via route I , whereas polymerization via route II may result in phase separation by nucleation and growth and , in the case of polymerization via route III , phase separation will occur by ...
... spinodal curve III . No phase separation occurs via route I , whereas polymerization via route II may result in phase separation by nucleation and growth and , in the case of polymerization via route III , phase separation will occur by ...
Page 194
... spinodal curve , defined now as 1 1 Xs ( f ) = 2 1 + NAf NB ( 1- . ( 6.11 ) Thus , a reasonable kinetic evolution equation is available for the beginning of the phase separation of a system of two components . The main problem in the ...
... spinodal curve , defined now as 1 1 Xs ( f ) = 2 1 + NAf NB ( 1- . ( 6.11 ) Thus , a reasonable kinetic evolution equation is available for the beginning of the phase separation of a system of two components . The main problem in the ...
Contents
Contents | 1 |
Nonlinear polymerization gelation and network formation | 14 |
4 | 40 |
Copyright | |
14 other sections not shown
Common terms and phrases
behaviour block copolymers Chapter Chem chemical components composition concentration constant conversion copolymerization crosslinking CTT diagram cure curve cyclization decrease deformation degree of polymerization dependence distribution Dušek EANCS Eichinger elastomers endlinking entanglements equation equilibrium Erman experimental Flory formed Frisch gel point gelation hard segments hard-segment content Ilavský increase initial injection moulding intramolecular reaction junction points kinetics linear Macosko Macromol Macromolecules mechanical microphase separation modulus molar mass molecular weight molecules monomer mould network chains network formation network materials network structure network-forming occur parameter phase separation Phys polymer networks Polymer Sci polyurethane predicted primary chains properties PUr-DETDA RA₂ ratio reactants reacted reactive groups RIM copolymer RIM materials ring structures rubber sample shear modulus shown in Figure soft segments soft-segment spinodal spinodal decomposition Stepto stress-strain Tcure temperature tensile thermodynamic thermosetting triol units values versus viscoelastic viscosity vitrification vitrification region volume fraction