Polymer Networks: Principles of Their Formation, Structure and Properties
Springer, 1998 - Science - 343 pages
Written by an international team of authors with a strong emphasis on the underlying chemistry, this book forms a timely, concise, and accessible evaluation of the fundamentals of polymer network formation, structure, and properties, and how these three aspects are interrelated.
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It is based on the erroneous precept that all the units in a polymerizing mixture
are connected to form an infinite tree at the gel point. Thus, according to equation
(2.19), for an RA^ polymerization, gelation occurs when p3 — 2/f. On average ...
The calculation of the number or concentration of EANCs is based on
considerations of the primary chains as building units. Each primary chain
contains j crosslinked units from which k bonds issue with infinite continuation.
Such a crosslinked ...
The exponent i of the variable z'xy identifies the number of bonds of x — » y type
issuing from the given building unit. Lower-case z as a variable is reserved for
the characterization of the number of bonds linking the building units.
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Nonlinear polymerization gelation and network formation
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