Principles of Polymer Chemistry |
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Contents
Early Investigations on Naturally Occurring Polymers | 4 |
Early Encounters with Condensation Polymers | 12 |
Vinyl Polymers | 20 |
CHAPTER II | 29 |
Classification of Polymers | 37 |
Addition Polymers from Unsaturated Monomers | 51 |
Polymerization of Cyclic Compounds | 57 |
Inorganic Polymers | 63 |
Addition Polymers | 334 |
Critical Conditions for the Formation of Infinite Networks | 348 |
Molecular Distributions in Polyfunctional Condensations | 361 |
Molecular Distributions in CrossLinked Systems | 378 |
Branching and CrossLinking in Vinyl Addition Polymers | 384 |
Summary | 392 |
CHAPTER X | 399 |
Calculation of Average Dimensions for Various Polymer Chain | 414 |
CHAPTER III | 69 |
Theory of the Reactivity of Large Molecules | 75 |
Kinetics of Degradation of Condensation Polymers | 83 |
Molecular Weights of Linear Condensation Polymers | 91 |
The Principle of Equal Reactivity | 102 |
The Conversion of Monomer to Polymer | 110 |
Chain Lengths | 132 |
Absolute Values of the Rate Constants for Individual Steps | 148 |
Inhibition and Retardation of Polymerization | 161 |
The Composition of Addition Copolymers | 178 |
The Rate of Addition Copolymerization | 199 |
Ionic Polymerization | 217 |
CHAPTER VI | 231 |
Structure and Arrangement of Units in Polymers from Dienes | 238 |
Steric Hindrance in Polymer Chains | 246 |
Nonlinearity in the MacroStructure of Vinyl Polymers | 256 |
Summary | 262 |
Osmotic Methods | 269 |
Determination of Molecular Weights and Polymer Dimensions | 283 |
Determination of Molecular Weights with the Ultracentrifuge | 303 |
CHAPTER VIII | 317 |
Configuration of Polymer Molecules in Dilute Solution | 423 |
CHAPTER XI | 432 |
The Structure of Vulcanized Rubber | 454 |
The Statistical Theory of Rubber Elasticity | 464 |
Experimental StressStrain Behavior of Vulcanized Rubbers | 470 |
The StressStrain Curve at High Elongations | 482 |
STATISTICAL THERMODYNAMICS | 495 |
Dilute Polymer Solutions | 519 |
CHAPTER XIII | 541 |
ponent in a Binary Solvent Mixture | 548 |
Phase Equilibria in Semicrystalline Systems | 563 |
Swelling of Network Structures | 576 |
CONFIGURATIONAL AND FRICTIONAL PROPERTIES | 595 |
Frictional Properties of the Polymer Molecule in Solution | 602 |
Intrinsic Viscosities of Non | 611 |
Frictional Coefficients | 626 |
GLOSSARY OF PRINCIPAL SYMBOLS | 640 |
AUTHOR INDEX | 653 |
663 | |
Common terms and phrases
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