Principles of Polymer Chemistry |
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... Initiator . 106 . 110 . 110 1b . Dependence of Initial Rates on the Concentrations of Initi- ator and Monomer 115 Parameters . 1c . Initiator Efficiencies 1d . Evaluation of Parameters le . The Course of the Conversion of Monomer to ...
... Initiator . 106 . 110 . 110 1b . Dependence of Initial Rates on the Concentrations of Initi- ator and Monomer 115 Parameters . 1c . Initiator Efficiencies 1d . Evaluation of Parameters le . The Course of the Conversion of Monomer to ...
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Contents
CHAPTER I | 3 |
Early Encounters with Condensation Polymers | 12 |
Vinyl Polymers | 20 |
CHAPTER II | 29 |
Classification of Polymers | 37 |
Addition Polymers from Unsaturated Monomers | 51 |
Polymerization of Cyclic Compounds | 57 |
Inorganic Polymers | 63 |
of Molecular Heterogeneity | 311 |
CHAPTER VIII | 317 |
Addition Polymers | 334 |
MOLECULAR WEIGHT DISTRIBUTIONS IN NONLINEAR | 347 |
Molecular Distributions in Polyfunctional Condensations | 361 |
Molecular Distributions in CrossLinked Systems | 378 |
Branching and CrossLinking in Vinyl Addition Polymers | 384 |
Summary | 392 |
CHAPTER III | 69 |
Theory of the Reactivity of Large Molecules | 75 |
Kinetics of Degradation of Condensation Polymers | 83 |
Molecular Weights of Linear Condensation Polymers | 91 |
Ring Formation vs Chain Polymerization | 100 |
CHAPTER IV | 106 |
1b Dependence of Initial Rates on the Concentrations of Initi | 115 |
1d Evaluation of Parameters | 122 |
1f Kinetics of Thermal Polymerization | 129 |
2d Chain Transfer with Solvents | 141 |
Absolute Values of the Rate Constants for Individual Steps | 148 |
Inhibition and Retardation of Polymerization | 161 |
The Composition of Addition Copolymers | 178 |
The Rate of Addition Copolymerization | 199 |
Ionic Polymerization | 217 |
CHAPTER VI | 231 |
Structure and Arrangement of Units in Polymers from Dienes | 238 |
Steric Hindrance in Polymer Chains | 246 |
Nonlinearity in the MacroStructure of Vinyl Polymers | 256 |
Summary | 262 |
Osmotic Methods | 269 |
Determination of Molecular Weights and Polymer Dimensions | 283 |
Determination of Molecular Weights with the Ultracentrifuge | 303 |
CHAPTER X | 399 |
Calculation of Average Dimensions for Various Polymer Chain | 414 |
Configuration of Polymer Molecules in Dilute Solution | 423 |
CHAPTER XI | 432 |
The Structure of Vulcanized Rubber | 454 |
The Statistical Theory of Rubber Elasticity | 464 |
Experimental StressStrain Behavior of Vulcanized Rubbers | 470 |
The StressStrain Curve at High Elongations | 482 |
STATISTICAL THERMODYNAMICS | 495 |
Dilute Polymer Solutions | 519 |
CHAPTER XIII | 541 |
ponent in a Binary Solvent Mixture | 548 |
Phase Equilibria in Semicrystalline Systems | 563 |
Swelling of Network Structures | 576 |
CONFIGURATIONAL AND FRICTIONAL PROPERTIES | 595 |
Frictional Properties of the Polymer Molecule in Solution | 602 |
Intrinsic Viscosities of Non | 611 |
Frictional Coefficients | 626 |
GLOSSARY OF PRINCIPAL SYMBOLS | 640 |
AUTHOR INDEX | 653 |
663 | |
668 | |
Common terms and phrases
according to Eq acid approximation atoms average degree average molecular weight bifunctional bond calculated CH₂ chain radicals chain transfer Chap Chem chemical potential coefficient components concentration condensation polymers configuration cross-linking crystalline crystallization curve decrease degree of polymerization depends dilute solution elastic elongation entropy equal equation equilibrium experimental expressed factor free energy functional groups gel point given heat Hence increase infinite initial interaction intramolecular intrinsic viscosity isoprene lattice length linear polymer measurements methacrylate methyl methyl methacrylate mole mole fraction monomer number average observed obtained occur osmotic osmotic pressure P. J. Flory parameter particles percent phase Phys plotted poly polyisobutylene polymer chain polymer molecules Polymer Sci polymer solutions polystyrene primary molecules probability proportional random ratio reaction reactivity represents rubber segments shown in Fig solvent species structural units styrene Substituting temperature termination theory thermodynamic tion total number unreacted v₁ vinyl acetate volume element vulcanized weight fraction zero