The Metal-Hydrogen System: Basic Bulk PropertiesMetal hydrides are of inestimable importance for the future of hydrogen energy. This unique monograph presents a clear and comprehensive description of the bulk properties of the metal-hydrogen system. The statistical thermodynamics is treated over a very wide range of pressure, temperature and composition. Another prominent feature of the book is its elucidation of the quantum mechanical behavior of interstitial hydrogen atoms, including their states and motion. The important topic of hydrogen interaction with lattice defects and its materials-science implications are also discussed thoroughly. This second edition has been substantially revised and updated. |
Contents
1 | |
9 | |
Hydrogen in Alloys 55 | 54 |
MetalHydrogen System | 91 |
Atomistic States of Hydrogen in Metals | 147 |
Diffusion | 303 |
Electronic Structure | 401 |
References 439 | 438 |
List of Symbols | 479 |
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Common terms and phrases
alloys approximation assuming average band becomes calculated caused changes Chem chemical comparison composition concentration condition configuration consistent correlation density dependence described determined diagram different diffusion diffusion coefficient direction displaced distance distribution effect electrons element energy estimated excitation expected experimental experiments expression fact factor formation frequency Fukai function given H atoms heat higher hydrides hydrogen atoms increase indicates interaction interstitial isotopes jumps larger lattice Lett limit lower measurements mechanism metals method motion nearly neutron Note observed obtained occupancy pairs parameter peak performed phase Phys potential pressure quantum range reaction region relaxation respectively sample scattering Sect shown in Fig shows similar smaller solid solubility solution structure Table temperature theory tion transition trapped tunneling vacancies values vibrational volume wave function