Mechanism and Theory in Organic Chemistry

Accts acetic acid catalysis addition alkyl Amer antarafacial aromatic atomic orbitals atoms base benzene Brønsted carbon carbonyl cation CH3 CH3 CH3 H chain Chem compounds conjugate conrotatory correlation cycloaddition cyclopropyl diagram double bond electrophilic elimination energy equilibrium example excited Figure formation formed Free Radicals G. A. Olah H CH3 H H H H₂O H3C CH3 H3C H Hoffmann hybrids hydrogen Ingold interaction intermediate ion pair ionization isotope effect J. K. Kochi k₁ kcal kcal mole-¹ ketones kinetic leaving group mechanism methyl migration molecular orbitals molecule nucleophile occur olefin oxygen P. D. Bartlett pericyclic Phys proton R. P. Bell R₁ racemic rate constant rate-determining react reactants reaction coordinate reactive rearrangement relative resonance ring S₁ Scheme Schleyer shown in Equation singlet solution solvent solvolysis stabilized stereochemistry steric Streitwieser structure substitution substrate sulfur Table Tetrahedron Lett tion tosylate transition triplet vibrational Winstein