Nanosystems: Molecular Machinery, Manufacturing, and ComputationWritten by a leading researcher in the field and one of its founders, Nanosystems is the first technical introduction to molecular nanotechnology - an emerging field that has sparked increasing interest and controversy. This groundbreaking book describes fundamental physical principles, components and devices, then examines applications including computers of unprecedented power and manufacturing systems able to build such products molecule by molecule. Nanosystems presents a comprehensive overview of how molecular manufacturing will make products by using nanoscale (billionths of a meter) mechanical and robotic technologies to guide the placement of molecules and atoms. Working with these fundamental building blocks of matter will enable designers to approach the limits of the possible: to build the smallest devices, the fastest computers, the strongest materials, and the highest quality products. By manipulating common molecules at high frequency, molecular manufacturing will make these products quickly, inexpensively, and on a large scale. Molecular manufacturing is the key to implementing molecular nanotechnologies, building systems to complex atomic specifications. This landmark work first presents the basic principles of physics and chemistry required to understand molecular machines. Then, Dr. Drexler describes computational models of molecules as mechanical systems, the effects of statistical mechanics, quantum uncertainty, damage mechanisms, and energy dissipation, and the fundamentals of mechanosynthesis - the use of mechanical devices to guide molecular reactions. Nanosystems then applies the analytical tools and concepts developed in the first section to the design ofnanomechanical components, devices, and systems. It describes nanomechanical gears, bearings, motors, sensors, logic gates, submicron 1000 MIPS computers (consuming 10(superscript -8) times as much power as comparable computers today), and systems able to join simple molecules to build complex products. The last section discusses how chemical, biochemical, and proximal probe technologies can be used to build complex molecular objects and how this capability can be used to implement molecular manufacturing. Bringing together physics, chemistry, mechanical engineering, and computer science, Nanosystems provides an indispensable introduction to the emerging field of molecular nanotechnology. |
From inside the book
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Page 121
... Transition state theories The previous chapter examined the effects of thermal excitation and quantum uncertainty in ... Transitions between potential wells 121 Transitions between potential wells.
... Transition state theories The previous chapter examined the effects of thermal excitation and quantum uncertainty in ... Transitions between potential wells 121 Transitions between potential wells.
Page 122
... transition rates . Accordingly , the following treatment is restricted to systems in which the potential wells are localized and distinctly bounded , permitting only vibrational motions within ( and transitions between ) wells . a ...
... transition rates . Accordingly , the following treatment is restricted to systems in which the potential wells are localized and distinctly bounded , permitting only vibrational motions within ( and transitions between ) wells . a ...
Page 126
... – exp ( −ħw / kT ) ] ̄1 i = 1 ( 6.13 ) 9 quant / 9 class 1.0 0.1 10 1 0.01 126 Transitions , Errors , and Damage Transition state theories Classical transition state theories Quantum transition state theories Tunneling.
... – exp ( −ħw / kT ) ] ̄1 i = 1 ( 6.13 ) 9 quant / 9 class 1.0 0.1 10 1 0.01 126 Transitions , Errors , and Damage Transition state theories Classical transition state theories Quantum transition state theories Tunneling.
Contents
Classical Magnitudes and Scaling Laws | 23 |
Potential Energy Surfaces | 36 |
Molecular Dynamics | 71 |
Copyright | |
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approximation assembly assumed atoms barrier bond carbon Chapter chemical chemistry classical complex components compression computational constraints continuum models covalent density described devices diamond diamondoid structures discussed displacement drive effects electronic electrostatic energy dissipation engineering entropy equilibrium estimated Figure force free energy frequency function gears geometry hydrogen input interactions interface intersystem crossing knob ligand logic rod macroscale magnitude manufacturing systems mass mechanochemical mechanosynthesis modulus moieties molecular manufacturing molecular mechanics molecular nanotechnology molecules motion nanomechanical systems nanometer nanoscale nonbonded nonbonded interactions operations oscillator parameters phonon pi bond position potential energy potential energy surface protein quantum mechanical radiation radical range rates reaction reactive reagent reagent moieties receptor resulting rotation scale Section shear sigma bonds sliding solution-phase specific speed stability statistical mechanics steric stiffness substantial surface synthesis temperature theoretical applied science thermal tion transition transition state theory typical values vibrational volume yields