Fractionation of Synthetic Polymers: Principles and PracticesLu-ho Tung |
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Page 98
... Flory , J. Chem . Phys . , 10 , 51 ( 1942 ) . P. J. Flory , Principles of Polymer Chemistry , Cornell Univ . Press , Ithaca , N. Y. , 1953 , Chap . 12 . M. L. Huggins , Physical Chemistry of High Polymers , Wiley , New York , 1958 ...
... Flory , J. Chem . Phys . , 10 , 51 ( 1942 ) . P. J. Flory , Principles of Polymer Chemistry , Cornell Univ . Press , Ithaca , N. Y. , 1953 , Chap . 12 . M. L. Huggins , Physical Chemistry of High Polymers , Wiley , New York , 1958 ...
Page 100
... Flory , J. Am . Chem . Soc . , 87 , 1833 ( 1965 ) . P. J. Flory , Disc . Faraday Soc . , 49 , 7 ( 1970 ) . I. Prigogine , A. Bellemans , and C. Naar - Colin , J. Chem . Phys . , 26 , 751 , ( 1957 ) . A. Abe and P. J. Flory , J. Am ...
... Flory , J. Am . Chem . Soc . , 87 , 1833 ( 1965 ) . P. J. Flory , Disc . Faraday Soc . , 49 , 7 ( 1970 ) . I. Prigogine , A. Bellemans , and C. Naar - Colin , J. Chem . Phys . , 26 , 751 , ( 1957 ) . A. Abe and P. J. Flory , J. Am ...
Page 224
... Flory - Huggins solution theory At first sight , σ is nearly constant , small p ( i.e. , higher phase Р o was assumed independent of X. independent of X in the range of separation temperature , T_ ) , but σ decreases gradually with an ...
... Flory - Huggins solution theory At first sight , σ is nearly constant , small p ( i.e. , higher phase Р o was assumed independent of X. independent of X in the range of separation temperature , T_ ) , but σ decreases gradually with an ...
Common terms and phrases
adsorption average molecular weight Benzene binary binodals Butanone calculated chain Chem chemical potential chromatogram chromatography cloud-point curve coefficient column component constant critical point cyclohexane decreases dependence determined effect elution equation equilibrium experimental Flory Flory-Huggins Flory-Huggins theory fractionation order fractions obtained free energy function given gradient graft copolymers heterogeneous homopolymers increases interaction parameter intrinsic viscosity Kamide LCST linear Makromol methacrylate Methanol method mixture molecular weight distribution molecules nonsolvent obtained by SPF original polymer phase diagrams phase separation plot poly polydispersity polymer concentration polymer solutions polymer-lean phase polymer-rich phase polymerization polystyrene precipitation ratio refractionation sample Schulz Schulz method Schulz-Zimm distribution shown in Fig solubility solvent SPF and SSF spinodal styrene technique theoretical theory thermodynamic titrations turbidity titrations virial virial coefficient viscosity volume fraction weight fraction Wesslau distribution Wesslau-type polymer XOXO zone spreading