Advanced Organic Chemistry: Reactions and synthesisPlenum Press, 1990 - Chemistry, Organic |
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Page 283
... therefore no intermediate , lie on the reaction path between reactants and adduct . 284 CHAPTER 6 CYCLOADDITIONS , UNIMOLECULAR REARRANGEMENTS , AND THERMAL 283 6 Cycloadditions, Unimolecular Rearrangements, and Thermal Eliminations.
... therefore no intermediate , lie on the reaction path between reactants and adduct . 284 CHAPTER 6 CYCLOADDITIONS , UNIMOLECULAR REARRANGEMENTS , AND THERMAL 283 6 Cycloadditions, Unimolecular Rearrangements, and Thermal Eliminations.
Page 316
Francis A. Carey. 316 CHAPTER 6 CYCLOADDITIONS , UNIMOLECULAR REARRANGEMENTS , AND THERMAL ELIMINATIONS 6.5 . [ 3,3 ] -Sigmatropic Rearrangements : Cope and Claisen Rearrangements The mechanistic basis of sigmatropic rearrangements was ...
Francis A. Carey. 316 CHAPTER 6 CYCLOADDITIONS , UNIMOLECULAR REARRANGEMENTS , AND THERMAL ELIMINATIONS 6.5 . [ 3,3 ] -Sigmatropic Rearrangements : Cope and Claisen Rearrangements The mechanistic basis of sigmatropic rearrangements was ...
Page 328
Francis A. Carey. 328 CHAPTER 6 CYCLOADDITIONS , UNIMOLECULAR REARRANGEMENTS , AND THERMAL ELIMINATIONS Claisen rearrangements of allyl phenyl ethers to ortho - allyl phenols were the first [ 3,3 ] -sigmatropic rearrangements to be ...
Francis A. Carey. 328 CHAPTER 6 CYCLOADDITIONS , UNIMOLECULAR REARRANGEMENTS , AND THERMAL ELIMINATIONS Claisen rearrangements of allyl phenyl ethers to ortho - allyl phenols were the first [ 3,3 ] -sigmatropic rearrangements to be ...
Contents
Alkylation of Nucleophilic Carbon Enolates and Enamines | 1 |
CONTENTS | 3 |
Polar Addition and Elimination Reactions | 6 |
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acetic acyl adduct alcohols aldehydes alkenes alkyl allylic amines anion aromatic aryl boron bromide C=C H C₂H carbanions carbon carbonyl carbonyl compounds carbonyl group carboxylic acids catalyst CH,O CH₂ CH₂OH CH3 CH CHAPTER 6 CYCLOADDITIONS Chem chiral chloride Claisen rearrangement CO,CH CO₂C₂H CO₂H cyclic cycloaddition reactions Diels-Alder reactions diene dienophile double bond E. J. Corey electron electrophilic ENAMINES enantioselectivity enol ether epoxides esters examples formation FUNCTIONAL GROUPS give Grignard reagents H CH H H H H H,C H,C CH H,C H,C H. C. Brown H₁C H₂ H₂C H₂O halides halogen hydride hydrogen hydroxyl intermediate intramolecular ketones Lewis acid lithium mechanism methyl molecules n-BuLi organoboranes organolithium organometallic oxidation oxygen Ph Ph PhCH₂O proton radical react reaction conditions REACTIONS INVOLVING reactive ring Scheme SECTION solvents step stereochemistry stereoselectivity steric structure Synth synthesis synthetic Tetrahedron Lett THERMAL ELIMINATIONS transition metal UNIMOLECULAR REARRANGEMENTS ylides