Advanced Organic Chemistry: Reactions and synthesisPlenum Press, 1990 - Chemistry, Organic |
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Page 658
... Allylic Oxidation 12.6.1 . Transition Metal Oxidants Carbon - carbon double bonds , besides being susceptible to addition of oxygen or cleavage , can also react at allylic positions ... allylic Allylic Oxidation Transition Metal Oxidants.
... Allylic Oxidation 12.6.1 . Transition Metal Oxidants Carbon - carbon double bonds , besides being susceptible to addition of oxygen or cleavage , can also react at allylic positions ... allylic Allylic Oxidation Transition Metal Oxidants.
Page 659
... allylic oxidations , the double bond is found in a position indicating that an " allylic shift " occurs during the oxidation . 659 SECTION 12.6 . ALLYLIC OXIDATION CH , CH3 Cro , -pyridine CH , CI , ( 58 % ) Ref . 156 Detailed ...
... allylic oxidations , the double bond is found in a position indicating that an " allylic shift " occurs during the oxidation . 659 SECTION 12.6 . ALLYLIC OXIDATION CH , CH3 Cro , -pyridine CH , CI , ( 58 % ) Ref . 156 Detailed ...
Page 798
... allylic alcohols , 661 in conversion of epoxides to allylic alcohols , 639 preparation from selenides , 347 thermal elimination reactions of , 347 Shapiro reaction , 266 , 374 Sharpless asymmetric epoxidation , 627-628 , 731-732 [ 2,3 ] ...
... allylic alcohols , 661 in conversion of epoxides to allylic alcohols , 639 preparation from selenides , 347 thermal elimination reactions of , 347 Shapiro reaction , 266 , 374 Sharpless asymmetric epoxidation , 627-628 , 731-732 [ 2,3 ] ...
Contents
Alkylation of Nucleophilic Carbon Enolates and Enamines | 1 |
CONTENTS | 3 |
Polar Addition and Elimination Reactions | 6 |
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acetic acyl adduct alcohols aldehydes alkenes alkyl allylic amines anion aromatic aryl boron bromide C=C H C₂H carbanions carbon carbonyl carbonyl compounds carbonyl group carboxylic acids catalyst CH,O CH₂ CH₂OH CH3 CH CHAPTER 6 CYCLOADDITIONS Chem chiral chloride Claisen rearrangement CO,CH CO₂C₂H CO₂H cyclic cycloaddition reactions Diels-Alder reactions diene dienophile double bond E. J. Corey electron electrophilic ENAMINES enantioselectivity enol ether epoxides esters examples formation FUNCTIONAL GROUPS give Grignard reagents H CH H H H H H,C H,C CH H,C H,C H. C. Brown H₁C H₂ H₂C H₂O halides halogen hydride hydrogen hydroxyl intermediate intramolecular ketones Lewis acid lithium mechanism methyl molecules n-BuLi organoboranes organolithium organometallic oxidation oxygen Ph Ph PhCH₂O proton radical react reaction conditions REACTIONS INVOLVING reactive ring Scheme SECTION solvents step stereochemistry stereoselectivity steric structure Synth synthesis synthetic Tetrahedron Lett THERMAL ELIMINATIONS transition metal UNIMOLECULAR REARRANGEMENTS ylides