Advanced Organic Chemistry: Reactions and synthesisPlenum Press, 1990 - Chemistry, Organic |
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Page xxv
... organoboranes 9.2 . Some one - carbon donors in alcohol and ketone synthesis using organoboranes 9.3 . Alkylation of trialkylboranes by a - halocarbonyl and related compounds 9.4 . Alkylation of organoboranes by a , ß - unsaturated ...
... organoboranes 9.2 . Some one - carbon donors in alcohol and ketone synthesis using organoboranes 9.3 . Alkylation of trialkylboranes by a - halocarbonyl and related compounds 9.4 . Alkylation of organoboranes by a , ß - unsaturated ...
Page 445
... organoboranes that were discussed in Chapter 4 are valuable methods for introducing functional groups into alkenes . In this section , we will discuss carbon - carbon bond - forming reactions of organoboranes . " Trivalent organoboranes ...
... organoboranes that were discussed in Chapter 4 are valuable methods for introducing functional groups into alkenes . In this section , we will discuss carbon - carbon bond - forming reactions of organoboranes . " Trivalent organoboranes ...
Page 788
... organoboranes , 205-206 aryl preparation from diazonium ions , 595 reaction with organoboranes , 205-206 aziridines , equilibria with azomethine ylides , 306-307 azo compounds , thermal elimination of nitrogen from , 339-340 Baeyer ...
... organoboranes , 205-206 aryl preparation from diazonium ions , 595 reaction with organoboranes , 205-206 aziridines , equilibria with azomethine ylides , 306-307 azo compounds , thermal elimination of nitrogen from , 339-340 Baeyer ...
Contents
Alkylation of Nucleophilic Carbon Enolates and Enamines | 1 |
CONTENTS | 3 |
Polar Addition and Elimination Reactions | 6 |
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acetic acyl adduct alcohols aldehydes alkenes alkyl allylic amines anion aromatic aryl boron bromide C=C H C₂H carbanions carbon carbonyl carbonyl compounds carbonyl group carboxylic acids catalyst CH,O CH₂ CH₂OH CH3 CH CHAPTER 6 CYCLOADDITIONS Chem chiral chloride Claisen rearrangement CO,CH CO₂C₂H CO₂H cyclic cycloaddition reactions Diels-Alder reactions diene dienophile double bond E. J. Corey electron electrophilic ENAMINES enantioselectivity enol ether epoxides esters examples formation FUNCTIONAL GROUPS give Grignard reagents H CH H H H H H,C H,C CH H,C H,C H. C. Brown H₁C H₂ H₂C H₂O halides halogen hydride hydrogen hydroxyl intermediate intramolecular ketones Lewis acid lithium mechanism methyl molecules n-BuLi organoboranes organolithium organometallic oxidation oxygen Ph Ph PhCH₂O proton radical react reaction conditions REACTIONS INVOLVING reactive ring Scheme SECTION solvents step stereochemistry stereoselectivity steric structure Synth synthesis synthetic Tetrahedron Lett THERMAL ELIMINATIONS transition metal UNIMOLECULAR REARRANGEMENTS ylides