Mechanism in Organic Chemistry |
Contents
MECHANISM AND REACTIVITY | 1 |
Energies of Transition States | 11 |
Isotope Effects | 16 |
Copyright | |
36 other sections not shown
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acetic acetone acid catalysis addition allyl Amer anion aqueous aromatic attack base benzene bromide butadiene C-H bond carbanion carbon atom carbonium ion carbonyl cation Chapter Chem chemistry chloride compounds concerted conjugate correlation cycloaddition cyclobutene cyclopropane derivatives deuterium ElcB electrons electrophilic elimination reactions energy equation equilibrium ester ethanol EtOH example exchange factor favoured Figure formation formed free-energy free-energy relationships free-radical ground-state H H H H. C. Brown H₂O halides hydrogen hydrogen-bonding hydrolysis increase interactions intermediate involved iodide ion-pair ionization isotope effect k₂ kcal kcal mole-¹ kinetic leaving group mechanism MeOH methyl methylene molecule non-bonded nucleophilic observed occurs olefin orbital oxygen phenyl polar possible proton proton-transfer racemization radical rate constant rate-determining ratio reactants reaction rate reactivity reacts reagent rearrangement relative ring SN2 reaction solution solvation solvolysis sp² stability step stereochemical steric steric effects structure studied substituent substitution substrate t-butyl Tetrahedron Letters tosylate transition-state Winstein