Foundations of Colloid Science, Volume 1Liquid suspension systems are the basic ingredients of paints, detergents, biological cells, and countless other systems of scientific and technological importance. This book presents the fundamental physical and chemical concepts necessary to the understanding of these systems and of colloid science in general. New ideas are introduced carefully and formulae are developed in full, with exercises to help the reader throughout. The frequent references to the many applications of colloid science will be especially helpful to beginning research scientists and people in industry, medicine and agriculture who often find their training in this area inadequate. Integrating developments from the time of colloid science's infancy forty years ago to its present state as a rigorous discipline, this intelligently assembled work elucidates a remarkable range of concepts, techniques, and behaviors. |
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Page 398
... chemical potential . This ' chemical ' part of the free energy change can be evaluated by noting that , when the last ion goes on , the chemical free energy decrease , △ μ , is exactly compensated by the electrical free energy increase ...
... chemical potential . This ' chemical ' part of the free energy change can be evaluated by noting that , when the last ion goes on , the chemical free energy decrease , △ μ , is exactly compensated by the electrical free energy increase ...
Page 647
... chemical potential of the water , since it has access to both phases I and II . The chemical potential of water in a solution is given by : μw = μ + RT In aw ( A6.1 ) where u is the chemical potential of pure water at 1 atmosphere ...
... chemical potential of the water , since it has access to both phases I and II . The chemical potential of water in a solution is given by : μw = μ + RT In aw ( A6.1 ) where u is the chemical potential of pure water at 1 atmosphere ...
Page 652
... chemical equilibrium , influence of particle size 269f chemical potential 51 at equilibrium 248 definition 641 interdependence in mixtures 645 of ions , in adsorption 398 of small particles 260 of surfactant , contributions to in ...
... chemical equilibrium , influence of particle size 269f chemical potential 51 at equilibrium 248 definition 641 interdependence in mixtures 645 of ions , in adsorption 398 of small particles 260 of surfactant , contributions to in ...
Contents
CHARACTERIZATION OF COLLOIDAL | 2 |
BEHAVIOUR OF COLLOIDAL DISPERSIONS | 49 |
PARTICLE SIZE AND SHAPE | 104 |
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adsorbed adsorption aggregation approximation aqueous assumed behaviour Brownian motion bulk calculated capillary chemical chemical potential coagulation coefficient Colloid interface Sci colloid science colloidal dispersions colloidal particles component constant contact angle crystal curvature curve density determined dielectric diffuse dipole distance distribution DLVO theory double layer droplet effect electrolyte electron electrostatic enthalpic entropy equation equilibrium Establish eqn Exercise experimental flocculation flow fluid force formula free energy frequency function given head group hydrocarbon interaction energy ions liquid material measured method micelle microscope molar mass molecular molecules monomer negative Note obtained occurs Overbeek phase plates polymer potential energy procedure quantity R₁ radius region repulsion result scattering sedimentation separation shear silver iodide solid solution solvent spheres spherical stabilizing moieties steric stabilization stress surface tension surfactant suspension temperature term theory thermodynamic vector velocity viscosity volume Waals x₁ Young-Laplace equation zero