Foundations of Colloid Science, Volume 1Liquid suspension systems are the basic ingredients of paints, detergents, biological cells, and countless other systems of scientific and technological importance. This book presents the fundamental physical and chemical concepts necessary to the understanding of these systems and of colloid science in general. New ideas are introduced carefully and formulae are developed in full, with exercises to help the reader throughout. The frequent references to the many applications of colloid science will be especially helpful to beginning research scientists and people in industry, medicine and agriculture who often find their training in this area inadequate. Integrating developments from the time of colloid science's infancy forty years ago to its present state as a rigorous discipline, this intelligently assembled work elucidates a remarkable range of concepts, techniques, and behaviors. |
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Page 567
... structure can at best be a statement of the average shape over some discrete time interval . The exchange that occurs between monomer molecules and those in the micelle occupies a time - scale of the order of 1-10 us ( Aniansson 1978 ) ...
... structure can at best be a statement of the average shape over some discrete time interval . The exchange that occurs between monomer molecules and those in the micelle occupies a time - scale of the order of 1-10 us ( Aniansson 1978 ) ...
Page 568
... structure ( Israelachvili et al . 1976 ) . We will however , defer more detailed discussion of these matters until later ( section 10.9 ) . We will first look at the phenomenology of micelle formation - what effect factors like ...
... structure ( Israelachvili et al . 1976 ) . We will however , defer more detailed discussion of these matters until later ( section 10.9 ) . We will first look at the phenomenology of micelle formation - what effect factors like ...
Page 621
... structure is less than 0.5kT per chain . By comparison , the free energy gained when a C12 chain is transferred from water to bulk n - alkane is ~ 20kT ( recall section 10.4 above ) . In the micelle one or two chains must be completely ...
... structure is less than 0.5kT per chain . By comparison , the free energy gained when a C12 chain is transferred from water to bulk n - alkane is ~ 20kT ( recall section 10.4 above ) . In the micelle one or two chains must be completely ...
Contents
CHARACTERIZATION OF COLLOIDAL | 2 |
BEHAVIOUR OF COLLOIDAL DISPERSIONS | 49 |
PARTICLE SIZE AND SHAPE | 104 |
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adsorbed adsorption aggregation approximation aqueous assumed behaviour Brownian motion bulk calculated capillary chemical chemical potential coagulation coefficient Colloid interface Sci colloid science colloidal dispersions colloidal particles component constant contact angle crystal curvature curve density determined dielectric diffuse dipole distance distribution DLVO theory double layer droplet effect electrolyte electron electrostatic enthalpic entropy equation equilibrium Establish eqn Exercise experimental flocculation flow fluid force formula free energy frequency function given head group hydrocarbon interaction energy ions liquid material measured method micelle microscope molar mass molecular molecules monomer negative Note obtained occurs Overbeek phase plates polymer potential energy procedure quantity R₁ radius region repulsion result scattering sedimentation separation shear silver iodide solid solution solvent spheres spherical stabilizing moieties steric stabilization stress surface tension surfactant suspension temperature term theory thermodynamic vector velocity viscosity volume Waals x₁ Young-Laplace equation zero