Plenary and Invited Lectures Presented at the 2nd International Symposium on Free Radical Polymerization, Kinetics and Mechanisms: Held in Santa Margherita Ligure, Genoa, Italy, 26-31 May 1996, Volumes 111-112Kenneth F. O'Driscoll, Saverio Russo |
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Page 150
... PROPAGATION REACTIONS Propagation in the Free - Radical Polymerization of Ethylene , 7,9 The propagation of ethylene has been studied previously because it is a homopolymerization without any substituent effects , which may obscure some ...
... PROPAGATION REACTIONS Propagation in the Free - Radical Polymerization of Ethylene , 7,9 The propagation of ethylene has been studied previously because it is a homopolymerization without any substituent effects , which may obscure some ...
Page 184
... propagation to TDB during the current one , i.e. the number of monomer units which have not been added by propagation to monomer in the last growth period . Table 1. Kinetic scheme . kinetic event radical entry in the particles ke Rw Ro ...
... propagation to TDB during the current one , i.e. the number of monomer units which have not been added by propagation to monomer in the last growth period . Table 1. Kinetic scheme . kinetic event radical entry in the particles ke Rw Ro ...
Page 305
... propagation and termination processes in free radical copolymerization were discussed on the basis of current experimental data . It was shown that the penultimate unit effect ( PUE ) in propagation is very general , affecting not only ...
... propagation and termination processes in free radical copolymerization were discussed on the basis of current experimental data . It was shown that the penultimate unit effect ( PUE ) in propagation is very general , affecting not only ...
Contents
A new form of controlled growth free radical polymerization | 13 |
Investigation of statistical block and graft copolymerizations using NMR | 25 |
Catalytic chain transfer for polymerization CCTP of methyl methacry | 37 |
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acid acrylate AIBN block copolymers calculated catalyst chain length chain transfer agents Chem compatibilizer component copolymer composition copolymerization crosslinked curve decomposition decrease deformation dependence determined dispersed distribution droplets effect emulsion polymerization end groups equation experimental Figure free radical polymerization function graft Hüthig & Wepf hydrogen hydrophobe increase initiator interaction interface k₁ kinetics Lotader Macromolecules macromonomer Makromol matrix measurements mechanism methyl methacrylate miniemulsion miscibility mixing mixture mol/L molecular weight monomer monomer reactivity ratios morphology observed obtained parameters phase separation PMMA polyamide polydispersities polymer polymer blends polymerization process polyolefins polystyrene primary radical produced propagation properties R₁ radical concentration rate coefficients rate constant reaction reactor rotation rubber particles samples scattering sensor sets simulation solution solvent spinodal structure styrene surfactant suspension polymerization temperature termination transfer constants values vinyl vinyl acetate viscosity volume fraction Wepf Wepf Verlag Zug CCC