Plenary and Invited Lectures Presented at the 2nd International Symposium on Free Radical Polymerization, Kinetics and Mechanisms: Held in Santa Margherita Ligure, Genoa, Italy, 26-31 May 1996, Volumes 111-112Kenneth F. O'Driscoll, Saverio Russo |
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Results 1-3 of 81
Page 58
... value of ka can then be estimated by using known values of the propagation rate constant of styrene ( kp • ~ 2,000 mol · 1L s - 1 at 120 oC [ 25 ] ) , and the previously discussed [ TEMPO ] st and [ CuX2 ] st values . It appears that ...
... value of ka can then be estimated by using known values of the propagation rate constant of styrene ( kp • ~ 2,000 mol · 1L s - 1 at 120 oC [ 25 ] ) , and the previously discussed [ TEMPO ] st and [ CuX2 ] st values . It appears that ...
Page 165
... values of the u and v parameters , together with the logarithms of the Tx , s values , in equations ( 4 ) and ( 5 ) yields , for the monomer reactivity ratios for the copolymerisation of 2 - chloro ( butadiene ) ( 1 ) and 2 ...
... values of the u and v parameters , together with the logarithms of the Tx , s values , in equations ( 4 ) and ( 5 ) yields , for the monomer reactivity ratios for the copolymerisation of 2 - chloro ( butadiene ) ( 1 ) and 2 ...
Page 167
... values of the monomer reactivity ratios are 0.04 , which may usefully be compared with the experimental values and the U , V predictions reported above . = 12 4.71 and 21 = Any other monomer X can be used in place of acrylonitrile as ...
... values of the monomer reactivity ratios are 0.04 , which may usefully be compared with the experimental values and the U , V predictions reported above . = 12 4.71 and 21 = Any other monomer X can be used in place of acrylonitrile as ...
Contents
A new form of controlled growth free radical polymerization | 13 |
Investigation of statistical block and graft copolymerizations using NMR | 25 |
Catalytic chain transfer for polymerization CCTP of methyl methacry | 37 |
Copyright | |
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Common terms and phrases
acid acrylate AIBN block copolymers calculated catalyst chain length chain transfer agents Chem compatibilizer component copolymer composition copolymerization crosslinked curve decomposition decrease deformation dependence determined dispersed distribution droplets effect emulsion polymerization end groups equation experimental Figure free radical polymerization function graft Hüthig & Wepf hydrogen hydrophobe increase initiator interaction interface k₁ kinetics Lotader Macromolecules macromonomer Makromol matrix measurements mechanism methyl methacrylate miniemulsion miscibility mixing mixture mol/L molecular weight monomer monomer reactivity ratios morphology observed obtained parameters phase separation PMMA polyamide polydispersities polymer polymer blends polymerization process polyolefins polystyrene primary radical produced propagation properties R₁ radical concentration rate coefficients rate constant reaction reactor rotation rubber particles samples scattering sensor sets simulation solution solvent spinodal structure styrene surfactant suspension polymerization temperature termination transfer constants values vinyl vinyl acetate viscosity volume fraction Wepf Wepf Verlag Zug CCC