Treatise on Materials Science and Technology, Volume 1 |
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Page 43
Fig . 22 . Representation of the different , energetically unique , surface sites for
molecules . of new , unique energy states that provide configurational entropy to
the system at the cost of an increase in enthalpy for each of these new states .
Fig . 22 . Representation of the different , energetically unique , surface sites for
molecules . of new , unique energy states that provide configurational entropy to
the system at the cost of an increase in enthalpy for each of these new states .
Page 47
22 and can determine the change in enthalpy caused by moving a molecule from
the kink position to one of these other states . This result would be approximately
given in terms of the change in number of first , second , and third nearest ...
22 and can determine the change in enthalpy caused by moving a molecule from
the kink position to one of these other states . This result would be approximately
given in terms of the change in number of first , second , and third nearest ...
Page 50
A similar situation exists for the total entropy change . To evaluate E1 , we must
first evaluate that portion of the total enthalpy change associated with the atomic
core rearrangement . where v , = 4€ / kTe and the change W . A . TILLER.
A similar situation exists for the total entropy change . To evaluate E1 , we must
first evaluate that portion of the total enthalpy change associated with the atomic
core rearrangement . where v , = 4€ / kTe and the change W . A . TILLER.
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addition alloys analysis angle applied approach associated assumed atoms average becomes bond boundary calculated complex composite concentration consider constants contribution crystal curvature curve decrease defined dependence deposition determined developed direction discussed displacement distance distribution dynamical effect elastic electron elements energy equal equation exist experimental fibers force fracture function given gives grain grain boundaries Group growth growth path illustrated increase indicate interaction interface internal friction interstitial iron laminate lattice layer length material matrix measured mechanism metal microstructural molecules nitrogen normal nucleation observed obtained occur oxygen particles peak phase plane position possible potential present produce properties region reinforcing relaxation respectively shown in Fig shows single Snoek peak solid solution strain strength stress structure substitutional surface Table temperature tungsten unit values volume waves