Polymer Motion in Dense Systems: Proceedings of the Workshop, Grenoble, France, September 23-25, 1987Dieter Richter |
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Page vii
... Figures ) Large Scale Motion Near the Glass Transition By T.A. Vilgis ( With 1 Figure ) Local Relaxation in Polymer Glasses Studied by NMR By H. Sillescu ( With 4 Figures ) Synchrotron - Excited Fluorescence Study of Local Dynamics in ...
... Figures ) Large Scale Motion Near the Glass Transition By T.A. Vilgis ( With 1 Figure ) Local Relaxation in Polymer Glasses Studied by NMR By H. Sillescu ( With 4 Figures ) Synchrotron - Excited Fluorescence Study of Local Dynamics in ...
Page 68
... Figure 3 : 3.5 1000 ( K - 1 ) 100'00 ŏ Proton spin lattice relaxation rates ( S - 1 ) Fig . 4 Phosphorus NMR relaxation rates as a function of reciprocal tempe- rature in P ( EO ) ( D3PO4 ) x for the composition x - 0.66 ( o , A , ) and ...
... Figure 3 : 3.5 1000 ( K - 1 ) 100'00 ŏ Proton spin lattice relaxation rates ( S - 1 ) Fig . 4 Phosphorus NMR relaxation rates as a function of reciprocal tempe- rature in P ( EO ) ( D3PO4 ) x for the composition x - 0.66 ( o , A , ) and ...
Page 267
... figure 4 which also shows data obtained for lower copolymer concentrations . From the intersection of the two straight lines the MST is calculated to be 79 ° C . A series of frames for this same copolymer solution are shown in figure 5 ...
... figure 4 which also shows data obtained for lower copolymer concentrations . From the intersection of the two straight lines the MST is calculated to be 79 ° C . A series of frames for this same copolymer solution are shown in figure 5 ...
Contents
Local Motions in Bulk Polymers By L Monnerie J L Viovy | 2 |
Large Scale Motion Near the Glass Transition | 18 |
SynchrotronExcited Fluorescence Study of Local Dynamics in Bulk | 37 |
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anisotropy autocorrelation function behaviour bond calculated Chem components concentration fluctuations conformational constraints copolymer correlation function corresponding crosslinking curve decay deformation density deuterated diffusion coefficient dynamic light scattering dynamics effect elastic energy entanglement equation experimental Figure fluorescence anisotropy frequency friction Fytas glass transition incoherent incoherent scattering interaction isotropic lattice length Lett light scattering linear lineshape Macromolecules measurements mixture modes molecular weight molecules monomer motion neutron scattering observed obtained orientation P.G. de Gennes parameter PDMS Phys plot polybutadiene polymer blends polymer chain polymeric polystyrene predicted protonated quasielastic quench radius of gyration range rods rotational Rouse model rubber sample scale scattered intensity scattering experiments scattering function segments shows simulations small angle solid solution spectra spectrum spin spinodal spinodal decomposition structure factor T₁ techniques temperature dependence theoretical theory tion tube values vector viscoelastic volume