Bimetallic catalysts: discoveries, concepts, and applications
Presents an account of the research on bimetallic catalysts. Focuses attention on the possibility of influencing the selectivity of chemical transformations on metal surfaces and preparing metal alloys in a highly dispersed state. Covers the validation and elucidation of the bimetallic cluster concept. Includes figures and tables.
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Selectivity Aspects of Bimetallic Catalysts
Bimetallic Systems of Immiscible Components
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absorber atom absorption edge absorption fine structure Academic Press alkanes alloys alumina aromatic hydrocarbons atomic ratio benzene bimetallic catalysts bimetallic clusters bulk calcined carbon monoxide cata Catal catalyst containing catalytic activity catalytic reforming Chem components composition coordination shell copper copper atoms copper EXAFS corresponding crystallites CuOs cycloalkanes cyclohexane decreases dehydrogenation electron energy ethane hydrogenolysis EXAFS data Group IB metal Group VIII metal highly dispersed hydrogen chemisorption hydrogen partial pressure hydrogenolysis activity interatomic distance isomerization isotherm lower lysts methylcyclopentane Mossbauer Mossbauer effect naphtha nearest neighbor nickel nickel-copper alloys obtained octane number OsCu osmium osmium and copper osmium-copper catalyst parameters partial pressure permission from Academic phase shift functions Phys platinum and iridium platinum-iridium catalyst platinum-rhenium catalyst reactions reference catalyst Reprinted with permission rhenium room temperature ruthenium-copper aggregates ruthenium-copper catalyst sample shown in Figure silica silica-supported Sinfelt space velocity spectroscopy studies surface atoms tion values X-ray diffraction yields