Bimetallic Catalysts: Discoveries, Concepts, and ApplicationsPresents an account of the research on bimetallic catalysts. Focuses attention on the possibility of influencing the selectivity of chemical transformations on metal surfaces and preparing metal alloys in a highly dispersed state. Covers the validation and elucidation of the bimetallic cluster concept. Includes figures and tables. |
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Results 1-3 of 17
Page 56
... Relative specific adsorption 0.5 Large Ru - Cu aggregates Highly dispersed Ru - Cu clusters 0.2 0.4 0.6 0.8 Cu / Ru atomic ratio Figure 4.2 Influence of the state of dispersion of ruthenium - copper catalysts on the relationship between ...
... Relative specific adsorption 0.5 Large Ru - Cu aggregates Highly dispersed Ru - Cu clusters 0.2 0.4 0.6 0.8 Cu / Ru atomic ratio Figure 4.2 Influence of the state of dispersion of ruthenium - copper catalysts on the relationship between ...
Page 153
... relative amounts of the two catalysts employed in the combined system . In our discussion up to this point , comparisons of catalysts have been made with regard to activities and yields of various products . The products have included ...
... relative amounts of the two catalysts employed in the combined system . In our discussion up to this point , comparisons of catalysts have been made with regard to activities and yields of various products . The products have included ...
Page 155
... relative to platinum catalysts cannot be attributed to a lower rate of accumulation of carbonaceous residues on the surface . For a given time on stream , the amount of such residues on the surface is not decreased by the presence of ...
... relative to platinum catalysts cannot be attributed to a lower rate of accumulation of carbonaceous residues on the surface . For a given time on stream , the amount of such residues on the surface is not decreased by the presence of ...
Common terms and phrases
absorber atom absorption edge absorption fine structure Academic Press adsorbed alkanes alloys alumina aromatic hydrocarbons atomic ratio atoms benzene bimetallic catalysts bimetallic clusters bulk calcined carbon monoxide cata Catal catalyst containing catalytic activity catalytic reforming Chem components composition coordination shell copper copper atoms copper EXAFS corresponding crystallites CuOs cycloalkanes cyclohexane decreases dehydrogenation electron energy EXAFS data fitting error Group IB metal Group VIII metal H₂ highly dispersed hydrogen chemisorption hydrogen partial pressure interatomic distance isomerization isotherm lower lysts methylcyclopentane Mössbauer Mössbauer effect n-heptane naphtha nearest neighbor nickel nickel-copper alloys obtained OsCu osmium osmium and copper osmium-copper catalyst parameters partial pressure permission from Academic phase shift functions Phys platinum and iridium platinum-iridium catalyst platinum-rhenium catalyst reactions reference catalyst Reprinted with permission rhenium room temperature ruthenium-copper aggregates ruthenium-copper catalyst sample shown in Figure silica silica-supported Sinfelt space velocity spectroscopy studies surface atoms tion values X-ray diffraction yields