Bimetallic Catalysts: Discoveries, Concepts, and ApplicationsPresents an account of the research on bimetallic catalysts. Focuses attention on the possibility of influencing the selectivity of chemical transformations on metal surfaces and preparing metal alloys in a highly dispersed state. Covers the validation and elucidation of the bimetallic cluster concept. Includes figures and tables. |
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Page 9
... studies of this selectivity phenomenon , with emphasis on hydrocarbon reac- tions such as isomerization of alkanes , aromatization of alkylcyclopentanes , dehydrogenation of cyclohexanes to aromatic hydrocarbons , and hydro- genolysis ...
... studies of this selectivity phenomenon , with emphasis on hydrocarbon reac- tions such as isomerization of alkanes , aromatization of alkylcyclopentanes , dehydrogenation of cyclohexanes to aromatic hydrocarbons , and hydro- genolysis ...
Page 50
... studies . " J. Vacuum Sci . Technol . 11 ( 7 ) : 212-224 ; 1974 . 14. Helms , C.R. and Sinfelt , J.H. " Electron spectroscopy ( ESCA ) studies of Ru - Cu catalysts . " Surface Sci . 72 : 229-242 ; 1978 . 15. Helms , C.R. and Yu , K.Y. ...
... studies . " J. Vacuum Sci . Technol . 11 ( 7 ) : 212-224 ; 1974 . 14. Helms , C.R. and Sinfelt , J.H. " Electron spectroscopy ( ESCA ) studies of Ru - Cu catalysts . " Surface Sci . 72 : 229-242 ; 1978 . 15. Helms , C.R. and Yu , K.Y. ...
Page 163
... studies , 20–25 magnetic properties , 20 , 22 preparation , 20 surface composition , 20 , 21 , 23 , 25 x - ray diffraction data , 20 , 21 Osmium - copper clusters : activity for : cyclohexane dehydrogenation , 58 cyclohexane ...
... studies , 20–25 magnetic properties , 20 , 22 preparation , 20 surface composition , 20 , 21 , 23 , 25 x - ray diffraction data , 20 , 21 Osmium - copper clusters : activity for : cyclohexane dehydrogenation , 58 cyclohexane ...
Common terms and phrases
absorber atom absorption edge absorption fine structure Academic Press adsorbed alkanes alloys alumina aromatic hydrocarbons atomic ratio atoms benzene bimetallic catalysts bimetallic clusters bulk calcined carbon monoxide cata Catal catalyst containing catalytic activity catalytic reforming Chem components composition coordination shell copper copper atoms copper EXAFS corresponding crystallites CuOs cycloalkanes cyclohexane decreases dehydrogenation electron energy EXAFS data fitting error Group IB metal Group VIII metal H₂ highly dispersed hydrogen chemisorption hydrogen partial pressure interatomic distance isomerization isotherm lower lysts methylcyclopentane Mössbauer Mössbauer effect n-heptane naphtha nearest neighbor nickel nickel-copper alloys obtained OsCu osmium osmium and copper osmium-copper catalyst parameters partial pressure permission from Academic phase shift functions Phys platinum and iridium platinum-iridium catalyst platinum-rhenium catalyst reactions reference catalyst Reprinted with permission rhenium room temperature ruthenium-copper aggregates ruthenium-copper catalyst sample shown in Figure silica silica-supported Sinfelt space velocity spectroscopy studies surface atoms tion values X-ray diffraction yields