Modern Molecular PhotochemistryDuring the last two decades the photochemistry of organic molecules has grown into an important and pervasive branch of organic chemistry. In Modern Molecular Photochemistry, the author brings students up to date with the advances in this field - the development of the theory of photoreactions, the utilization of photoreactions in synthetic sequences, and the advancement of powerful laser techniques to study the mechanisms of photoreactions. |
Contents
2 | 8 |
1 | 9 |
Electronic Orbitals Configurations and States | 17 |
2 | 21 |
9 | 28 |
11 | 36 |
5 | 43 |
4 | 52 |
63 | 144 |
72 | 150 |
Photophysical Radiationless Transitions | 153 |
69 | 174 |
74 | 179 |
8 | 180 |
Theoretical Organic Photochemistry | 199 |
Mechanistic Organic Photochemistry | 232 |
6 | 64 |
8 | 70 |
Emission of Light | 76 |
5 | 91 |
7 | 103 |
9 | 112 |
11 | 132 |
56 | 137 |
13 | 143 |
Energy Transfer | 296 |
Photoaddition and Photosubstitution Reactions | 362 |
Cycloaddition Reactions | 414 |
Isomerizations and Rearrangements | 473 |
Photofragmentation Reactions | 526 |
Singlet Oxygen and Chemiluminescent | 579 |
Epilogue | 615 |
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Common terms and phrases
absorption abstraction acceptor addition allowed aromatic atom benzene bond Chem chemical compounds configuration consider correlation corresponds coupling depends diagram diradical direct donor effect efficiency electron emission emission spectrum energy transfer ethylene example exciplex excited expected experimental factors field Figure fluorescence formation function geometry given ground hydrogen important initial interaction intermediate intersystem crossing involved jump kcal/mole ketones Letters lifetime light magnetic magnitude measured mechanism mixing molecular molecule motion nuclear observed occur orbital organic oscillator pair pathway phosphorescence photochemical photoreactions Phys possess possible probability processes pure quantum quantum mechanical quenching radiative radical rate constant reaction reactive Reference relative representative result ring rule S₁ sensitizer separation singlet solvent species spectrum spin spin-orbit structure surface symmetry T₁ Table temperature triplet Type undergo vibrational wave yield Zero Order