Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 489
... chromophore is inherently op- tically active and ( 2 ) when a chromophore is optically active by virtue of the perturbing effects of a static asymmetric environment . In order for the first case to obtain , the transition itself and the ...
... chromophore is inherently op- tically active and ( 2 ) when a chromophore is optically active by virtue of the perturbing effects of a static asymmetric environment . In order for the first case to obtain , the transition itself and the ...
Page 490
... chromophore , another chromophore , an ion , a solvent molecule , etc. The kind of perturbation which gives rise to the one - electron mechanism is the time - averaged static field in which the chromophore is located . [ The " dynamic ...
... chromophore , another chromophore , an ion , a solvent molecule , etc. The kind of perturbation which gives rise to the one - electron mechanism is the time - averaged static field in which the chromophore is located . [ The " dynamic ...
Page 491
... chromophore belongs ; Schellman also demon- strated that the higher the symmetry of the chromophore , the higher the multipole ( i.e. , monopole , dipole ) term in V needed to induce optical activity . Both of these findings suggest ...
... chromophore belongs ; Schellman also demon- strated that the higher the symmetry of the chromophore , the higher the multipole ( i.e. , monopole , dipole ) term in V needed to induce optical activity . Both of these findings suggest ...
Contents
F Density and Composition | 16 |
Direct Volume Change | 22 |
Density | 32 |
Copyright | |
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a-helix absorption acid Amer angle B-structure band Biochem Biochemistry Biol c₂ calculated CD spectra Chem chemical potential chromophore coefficient conformation constant Cotton effects cross-section denaturation determined dialyzate difference diffusible components dilute Donnan electron density enzyme equation equilibrated equilibrium exciton experimental function gm/ml grams helical helix hemocyanin hemoglobin intensity interaction Kratky Kupke Linderstrøm-Lang macromolecules magnetic measurements membrane method mixture molal molecular weight molecule monomer myoglobin negative nondiffusible components nonideality number of moles obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides positive potential procedure protein component protein concentration protein solution radius of gyration random coil residues rotational strength salt sample Scatchard Schellman Section shape small-angle scattering solvent solvent medium spectrum sphere structure subunits temperature Tinoco tion transition v₂ volume change wavelength zero