Physical Principles and Techniques of Protein Chemistry, Part 3 |
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Page 368
However , this mechanism cannot explain the inherent optical activity of
molecules with single chromophores nor the strong optical activity sometimes
shown by very weak magnetically allowed but electrically forbidden transitions (
in an ...
However , this mechanism cannot explain the inherent optical activity of
molecules with single chromophores nor the strong optical activity sometimes
shown by very weak magnetically allowed but electrically forbidden transitions (
in an ...
Page 501
The Electric - Magnetic Coupling Mechanism The model system will now consist
of two amide chromophores and a symmetry rule for the electric - magnetic
coupling mechanism will be developed in terms of the coupling existing between
the n ...
The Electric - Magnetic Coupling Mechanism The model system will now consist
of two amide chromophores and a symmetry rule for the electric - magnetic
coupling mechanism will be developed in terms of the coupling existing between
the n ...
Page 505
The conclusions just reached can be summarized in terms of a simple symmetry
rule for the electric - magnetic coupling mechanism for situations in which y2 I
R211 m : if R21 is normal to the plane of the chromophore exhibiting the ...
The conclusions just reached can be summarized in terms of a simple symmetry
rule for the electric - magnetic coupling mechanism for situations in which y2 I
R211 m : if R21 is normal to the plane of the chromophore exhibiting the ...
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addition amount angle appears applied approximately band beam becomes calculated Chem compared complex component concentration conformation constant containing contribution corresponding creatine cross-section density dependence described determined diffusible dilute discussed effect electron electron density enzyme equation equilibrium et al example experimental experiments factor field function given gives gyration increase indicated intensity interaction Kratky length magnetic mass means measurements membrane method mole molecular weight molecule negative observed obtained optical activity parameters particles plot positive possible procedure protein solution pulse radius of gyration range ratio reference region relative residues respectively rotational strength sample scattering curve shape shown shows side similar small-angle solvent specific specific volume spectra spectrum sphere structure studies subunits Table temperature theoretical theory tion transition usually various varying volume wavelength X-ray zero