Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 305
... parameters representing a component band and B contains additional parameters representing a baseline . No special form for the model function is assumed , however , in the following analysis . The condition that S in Eq . ( 1 ) be a ...
... parameters representing a component band and B contains additional parameters representing a baseline . No special form for the model function is assumed , however , in the following analysis . The condition that S in Eq . ( 1 ) be a ...
Page 317
... parameters in the fitting function F. The quantity nm is the number of degrees of freedom for the optimization . Unbiased estimates of the standard deviations of the parameter values may be calculated from the relation đj = ở ( c − 1 ) ...
... parameters in the fitting function F. The quantity nm is the number of degrees of freedom for the optimization . Unbiased estimates of the standard deviations of the parameter values may be calculated from the relation đj = ở ( c − 1 ) ...
Page 335
... PARAMETERS TO GIVE BEST FIT OF MODEL FUCTIONS F ( 1 ) -F ( N ) TO OBSERVED DATA Y ( 1 ) -Y ( N ) . UP TO LEM - 1 OF THE PARAMETERS MAY BE CONSTRAINED TO RETAIN PRESELECTED VALUES . IN THIS VERSION EACH Y ( 1 ) IS ASSOCIATED WITH A ...
... PARAMETERS TO GIVE BEST FIT OF MODEL FUCTIONS F ( 1 ) -F ( N ) TO OBSERVED DATA Y ( 1 ) -Y ( N ) . UP TO LEM - 1 OF THE PARAMETERS MAY BE CONSTRAINED TO RETAIN PRESELECTED VALUES . IN THIS VERSION EACH Y ( 1 ) IS ASSOCIATED WITH A ...
Contents
F Density and Composition | 16 |
Direct Volume Change | 22 |
Density | 32 |
Copyright | |
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a-helix absorption acid Amer angle B-structure band Biochem Biochemistry Biol c₂ calculated CD spectra Chem chemical potential chromophore coefficient conformation constant Cotton effects cross-section denaturation determined dialyzate difference diffusible components dilute Donnan electron density enzyme equation equilibrated equilibrium exciton experimental function gm/ml grams helical helix hemocyanin hemoglobin intensity interaction Kratky Kupke Linderstrøm-Lang macromolecules magnetic measurements membrane method mixture molal molecular weight molecule monomer myoglobin negative nondiffusible components nonideality number of moles obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides positive potential procedure protein component protein concentration protein solution radius of gyration random coil residues rotational strength salt sample Scatchard Schellman Section shape small-angle scattering solvent solvent medium spectrum sphere structure subunits temperature Tinoco tion transition v₂ volume change wavelength zero