Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 396
... positive . Cotton effect centered at 198-200 nm of large rotational strength . The second ( x ) is polarized in the direction of the interchain hydrogen bonds and gives rise to a smaller positive Cotton effect centered at 194–196 nm ...
... positive . Cotton effect centered at 198-200 nm of large rotational strength . The second ( x ) is polarized in the direction of the interchain hydrogen bonds and gives rise to a smaller positive Cotton effect centered at 194–196 nm ...
Page 415
... positive b'o - could be ex- plained simply by adding positive Cotton effects that correspond to the tyrosyl chromophore . Damle ( 1970 ) has also presented ORD and CD data for poly - L - tyro- sine in trimethyl phosphate showing , from ...
... positive b'o - could be ex- plained simply by adding positive Cotton effects that correspond to the tyrosyl chromophore . Damle ( 1970 ) has also presented ORD and CD data for poly - L - tyro- sine in trimethyl phosphate showing , from ...
Page 543
... positive dichroism near 280 , reveals no distinct band . A significant result here is the sharp con- formation dependence and the fact that the band near 270 nm is positive , in contrast to that of N - acetyl - L - tyrosineamide in ...
... positive dichroism near 280 , reveals no distinct band . A significant result here is the sharp con- formation dependence and the fact that the band near 270 nm is positive , in contrast to that of N - acetyl - L - tyrosineamide in ...
Contents
F Density and Composition | 16 |
Direct Volume Change | 22 |
Density | 32 |
Copyright | |
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a-helix absorption acid Amer angle B-structure band Biochem Biochemistry Biol c₂ calculated CD spectra Chem chemical potential chromophore coefficient conformation constant Cotton effects cross-section denaturation determined dialyzate difference diffusible components dilute Donnan electron density enzyme equation equilibrated equilibrium exciton experimental function gm/ml grams helical helix hemocyanin hemoglobin intensity interaction Kratky Kupke Linderstrøm-Lang macromolecules magnetic measurements membrane method mixture molal molecular weight molecule monomer myoglobin negative nondiffusible components nonideality number of moles obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides positive potential procedure protein component protein concentration protein solution radius of gyration random coil residues rotational strength salt sample Scatchard Schellman Section shape small-angle scattering solvent solvent medium spectrum sphere structure subunits temperature Tinoco tion transition v₂ volume change wavelength zero