Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 428
... transition it is prefer- able to study the far - UV Cotton effects in more detail . The most thoroughly characterized conformational transition , both the- oretically and experimentally , is the helix - to - coil transition which occurs ...
... transition it is prefer- able to study the far - UV Cotton effects in more detail . The most thoroughly characterized conformational transition , both the- oretically and experimentally , is the helix - to - coil transition which occurs ...
Page 490
... transitions optically active . ( Note that an inherently optically active transition may acquire additional optical activity in this way . ) Such a perturbing environment could be produced by the remainder of the mole- cule containing ...
... transitions optically active . ( Note that an inherently optically active transition may acquire additional optical activity in this way . ) Such a perturbing environment could be produced by the remainder of the mole- cule containing ...
Page 501
... transition a of group 1 ) and the sition of the other amide ( transition b of group 2 ) . From Eq . ( 48a ) , the appropriate expression for the rotational strength R1a of the n1- sition here is21 tran- Ria = + V12Im [ μ2 m1 ] 2λöλa2 hc ...
... transition a of group 1 ) and the sition of the other amide ( transition b of group 2 ) . From Eq . ( 48a ) , the appropriate expression for the rotational strength R1a of the n1- sition here is21 tran- Ria = + V12Im [ μ2 m1 ] 2λöλa2 hc ...
Contents
F Density and Composition | 16 |
Direct Volume Change | 22 |
Density | 32 |
Copyright | |
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a-helix absorption acid Amer angle B-structure band Biochem Biochemistry Biol c₂ calculated CD spectra Chem chemical potential chromophore coefficient conformation constant Cotton effects cross-section denaturation determined dialyzate difference diffusible components dilute Donnan electron density enzyme equation equilibrated equilibrium exciton experimental function gm/ml grams helical helix hemocyanin hemoglobin intensity interaction Kratky Kupke Linderstrøm-Lang macromolecules magnetic measurements membrane method mixture molal molecular weight molecule monomer myoglobin negative nondiffusible components nonideality number of moles obtained optical activity osmometers osmotic pressure parameter partial specific volume particles peptide Phys Pilz plot polymer polypeptides positive potential procedure protein component protein concentration protein solution radius of gyration random coil residues rotational strength salt sample Scatchard Schellman Section shape small-angle scattering solvent solvent medium spectrum sphere structure subunits temperature Tinoco tion transition v₂ volume change wavelength zero