Polymer Chemistry

Front Cover
Springer Science & Business Media, Dec 6, 2012 - Science - 652 pages
There is, at present, no scarcity of polymer textbooks in the English language. Some of them attempt to cover the entire field, others focus their attention on certain parts of it, e.g., organic chemistry, physical chemistry, solid state physics, etc. This situation must necessarily raise the question, "Why publish another book?" and, even more, "Why translate a book which exists already in German?" and is to a lesser or greater extent legible and comprehensible to many English speaking scientists. It appears that a justification can be found in the special character of its content and presentation. As far as content is concerned, Vollmert's book is more encompassing than most existing treatises and, in this sense, almost represents a hybrid between a "textbook" and a "handbook." Numerous figures and tables convey directly a wealth of data. On the other hand, the text is designed to be educational and, in many instances, goes a long way to explain why certain properties are observed and why certain processes take place. These excursions into the intellectual clarification of somewhat complicated phenomena are a refreshing and unusual interruption of the main stream which presents synthesis, characteriza tion and properties of polymeric systems in the classical way.
 

Contents

Introduction
1
Natural and synthetic macromolecules
7
Synthesis and Reactions of Macromolecular Compounds
40
Chain termination
58
Kinetics of radical polymerization
73
Copolymerization
94
Block and graftcopolymers 148
148
Ionic polymerization
163
Molecular weight distribution
372
Determination of the distribution curve by means
389
Other methods of fractionation 403
403
Theoretical derivation of the distribution function
411
Molecular weight averages 425
425
The form of the macromolecule molecular shape
435
The dependence of the coil diameter 2 and
445
The macromolecular solution
488

Synthesis of macromolecules with heteroatoms in the chain
206
The technique of polycondensation 234
234
Polymers from heterocyclic compounds and formaldehyde
244
Polyformaldehyde 251
251
Graft copolymerization by means of radicals 291
291
Graftcopolymers through copolymerization 299
299
Purification of polymers
305
The Properties of the Individual Macromolecule
332
States of Macromolecular Aggregation
514
The gel state
543
The rubberelastic state viscoelasticity
561
The solid state
572
Appendix
629
184
633
305
647
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