Polymer Molecular Weights, (2 Part)Philip E. Slade This two-part book incorporates in one definitive publication the major techniques used to determine the molecular weights of polymers as presented by some of the most respected authorities in the field. Part I of this practical guide covers membrane osmometry, end group determinations, absolute colligative property methods, and light-scattering methods. Discussions on theoretical background are included for every experimental procedure, as are examples of applications in polymeric processes. The information contained in Polymer Molecular Weights cannot be found in any other single publication, making it the most convenient source of information on molecular weight measurement for polymer chemists and physicists, analytical and physical chemists, biochemists, and other scientists in the plastics and synthetic fiber industries. Book jacket. |
Contents
Chapter | 1 |
GEL PERMEATION CHROMATOGRAPHY | 6 |
Molecular Weight Distribution | 7 |
Chapter 3 | 31 |
ABSOLUTE COLLIGATIVE PROPERTY METHODS | 79 |
LIGHT SCATTERING FROM SOLUTIONS OF MACROMOLECULES | 161 |
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Common terms and phrases
acid aliphatic aliphatic amine amine end groups Anal apparatus applicable aromatic average molecular weight boiling temperature Bonnar calculation calibration carboxyl end groups cell chain Chem Chemical colligative property component concentration condensation polymers cryoscopic cryoscopic constant curvature described dilution ebulliometer end group analysis end group methods end point equation experimental extrapolation function high molecular weight hydroxyl hydroxyl end groups incident beam instrument Interscience Kc/R Kokle least squares light scattering light-scattering limit linear linear least squares liquid Makromol measured membrane membrane osmometry methanol molecular weight determination molecules nonideality number average molecular nylon obtained optical osmometer osmometry osmotic pressure Phys plot polyamides polyesters Polymer Sci polymer solutions polymerization potentiometric procedure reagent reference solute Reprinted from Ref sample scattering factor second virial coefficient segments sensor shown in Fig soluble solvent Stross techniques thermistors third virial titration vapor pressure osmometry vinyl polymers virial coefficient zero point error