Statistical Mechanics |
Contents
INTRODUCTION AND REVIEW | 1 |
THE CANONICAL ENSEMBLE | 35 |
Chapter 5 | 81 |
Copyright | |
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Additional Reading approximation assume atoms Boltzmann equation calculate canonical ensemble Chapter Chem classical collision consider coordinates correlation function crystal Debye defined denote density Derive Eq diatomic molecules diffusion dipole discuss electronic entropy equations of motion evaluate expansion expression Figure fluid Fourier transform free energy frequency gases given gives Hamiltonian hard-sphere heat capacity Helmholtz free energy ideal gas integral intermolecular potential kinetic lattice Lennard-Jones linear liquid molecular dynamics momentum N₁ particles partition function Percus-Yevick phase space Phys pressure Problem quantity quantum mechanical r₁ radial distribution function radiation rotational scattering second virial coefficient Section Show solution spheres statistical mechanics statistical thermodynamics summation symmetric Table temperature theory thermal time-correlation function tion values variables vector velocity vibrational virial coefficient virial expansion wave function write York zero