Conjugated Conducting Polymers |
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Page 81
The ENDOR spectra for the Feast - type polyacetylene was seen to be
temperature - independent up to 200 K and the half width of the soliton was found
to correspond to 12 CH units ( i . e . total width = 25 units ) . The authors believe
that the ...
The ENDOR spectra for the Feast - type polyacetylene was seen to be
temperature - independent up to 200 K and the half width of the soliton was found
to correspond to 12 CH units ( i . e . total width = 25 units ) . The authors believe
that the ...
Page 146
2 ) the length of undisturbed chains is only about 40 CH units . In the Shirakawa
material , on the other hand , many chains are in a disordered environment . 3 . 1
. 3 Disorder Along the Chains So far the discussion of the one - dimensional ...
2 ) the length of undisturbed chains is only about 40 CH units . In the Shirakawa
material , on the other hand , many chains are in a disordered environment . 3 . 1
. 3 Disorder Along the Chains So far the discussion of the one - dimensional ...
Page 181
Of particular interest is the influence of the bond that links the monomer units . In
the case of polypyrrole , the optical gap is theoretically expected to decrease from
3 . 2 eV to 2 . 6 eV if this bond length is reduced from 1 . 49 Å to 1 . 4 Å [ 4 . 19 ] .
Of particular interest is the influence of the bond that links the monomer units . In
the case of polypyrrole , the optical gap is theoretically expected to decrease from
3 . 2 eV to 2 . 6 eV if this bond length is reduced from 1 . 49 Å to 1 . 4 Å [ 4 . 19 ] .
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Contents
Introduction | 1 |
An Overview of the Theory of rConjugated Polymers | 7 |
References | 114 |
Copyright | |
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Common terms and phrases
absorption addition applied approach approximation atoms band behaviour bipolarons bond bond alternation calculations carriers chain charged chemical concentration conductivity configuration conjugated polymers contribution correlation corresponding Coulomb Coulomb interactions coupling decreases defects density dependence described determined dimerization discussed dopant doping effects electron electron-electron energy excitations expected experimental experiments field finite frequency function give ground Hamiltonian hopping Hubbard important increase indicated interactions interpretation involving lattice leads length Lett limit localized magnetic materials measurements metallic methods modes molecules motion neutral nuclear observed obtained optical pair parameter peak phonon Phys Physics polarons polyacetylene polyenes polymers position properties range relaxation resonance respect samples Sect separation shift shown shows similar single soliton spectra spectrum spin structure studies symmetry Synth temperature theoretical theory trans-(CH transition units valence values whereas