Polymers at Interfaces: Novel Copolymer Designs for Interfacial Strengthening |
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Page 2
... anionic polymerization , the development of other living polymerization systems which impart control of architecture and functionality would allow for the study of more copolymers . Therefore , with the continued application of novel ...
... anionic polymerization , the development of other living polymerization systems which impart control of architecture and functionality would allow for the study of more copolymers . Therefore , with the continued application of novel ...
Page 48
... anionic polymerization can be difficult because monomers typically have very different reactivities toward the propagating anionic chain end . In our specific case , the targets were styrene / 4 - methylstyrene random copolymers . Since ...
... anionic polymerization can be difficult because monomers typically have very different reactivities toward the propagating anionic chain end . In our specific case , the targets were styrene / 4 - methylstyrene random copolymers . Since ...
Page 53
... polymerization from the metalated sites located along the polymer chain . Graft polymerization from metalated copolymer Since the graft polymerization is designed to proceed by an anionic mechanism , a suitably protected monomer must be ...
... polymerization from the metalated sites located along the polymer chain . Graft polymerization from metalated copolymer Since the graft polymerization is designed to proceed by an anionic mechanism , a suitably protected monomer must be ...
Contents
List of Schemes XV | 10 |
The Role of Polymer Architecture in Strengthening | 31 |
The Role of Functional Groups in Strengthening | 84 |
1 other sections not shown
Common terms and phrases
4-acetoxystyrene 4-methoxystyrene anionic polymerization areal chain density benzamide benzamide copolymers block copolymers broad Chain Density chains/nm² chain pull-out chain scission cm¹ Copolymer Areal Chain copolymer chains copolymer composition copolymer layer thickness craze Creton degree of polymerization deprotected deuterated polystyrene deuterium diblock dichloromethane entanglement equiv Figure fraction of deuterated fraction of dPS fracture plotted fracture toughness Fracture Toughness J/m² fracture toughness measurements Fracture toughness plotted Fréchet graft copolymers H NMR H-bonding homopolymer hydrogen bonding hydroxystyrene interface after fracture interfacial fracture toughness interfacial strengthening Kramer low areal chain Macromolecules metalation methanol molecular weight distribution monomer Mw/Mn NMR spectra observed pentablock copolymer phase boundary poly(4-hydroxystyrene polymer polymeric initiator polystyrene side primary benzamide proton PS/PVP interface reinforced PVP plates PVP side pyridine radical polymerization random copolymer resonances Scheme segments side after fracture side of interface solution styrene styrene-dg superbase thickness and areal triblock