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The Role of Polymer Architecture in Strengthening
The Role of Functional Groups in Strengthening
Characterization of Random Block and Graft
4-acetoxystyrene 4-methoxystyrene anionic polymerization areal chain density benzamide benzamide copolymers block copolymers broad chain pull-out chain scission chains/nm2 Copolymer Areal Chain copolymer chains copolymer layer thickness copolymer with f copolymerization craze Creton degree of polymerization deprotected deuterated polystyrene deuterium diblock dichloromethane dPSi-f entanglement equiv Figure fraction of deuterated fracture plotted fracture toughness fracture toughness measurements Fracture toughness plotted Frechet graft copolymers H NMR H-bonding homopolymer hydrogen bonding hydroxystyrene interface after fracture interfacial fracture toughness interfacial strengthening Kramer low areal chain Macromolecules metalation methanol molar fraction molecular weight distribution monomer Mw/Mn NMR spectra observed pentablock copolymer phase boundary poly(4-hydroxystyrene poly(styrene-d8 polymer polymeric initiator polystyrene side precipitated into excess primary benzamide proton PS(OH PVP plates PVP side pyridine radical polymerization random copolymer resonances Scheme SEC Mn segments side after fracture side of interface solution studies styrene styrene-d8 superbase thickness and areal triblock Xrcp