Statistical Mechanics

Additional Reading approximation assume atoms Boltzmann equation calculate canonical ensemble Chapter Chem classical collision consider constant coordinates correlation function Debye defined denote density Derive Eq diatomic molecules diffusion dipole discuss electronic ensemble average entropy equilibrium evaluate expansion experimental expression Figure fluid Fourier transform free energy frequency gases given gives GR GR Hamiltonian hard-sphere heat capacity Helmholtz free energy ideal gas integral intermolecular potential kinetic lattice Lennard-Jones linear liquid molecular dynamics momentum N₁ n₂ particles partition function Percus-Yevick phase space Phys pressure Problem properties quantity quantum mechanical r₁ radial distribution function radiation rotational scattering Section Show solution statistical mechanics statistical thermodynamics summation Table temperature theory thermal time-correlation function tion values variables vector velocity vibrational virial coefficient virial expansion volume wave function write York zero