Advances in Elastomers and Rubber ElasticityJoginder Lal, James E. Mark The present book is a sequel to "Elastomers and Rubber Elasticity," edited by J.E. Mark and J. Lal and published by the American Chemical Society in 1982. It is also based on papers presented at an ACS Symposium, sponsored by the Division of Polymer Chemistry, Inc., in this case one held in Chicago in September of 1985. The keynote speaker was to have been Pro fessor Paul J. Flory, and his untimely death just prior to the symposium was a tremendous loss to all of polymer science, in particular to those in terested in elastomeric materials. It is to his memory that this book is dedicated. There has been a great deal of progress in preparing and studying elas tomers since the preceding symposium, which was in 1981. In the case of the synthesis and curing of elastomers, much of the background necessary to an appreciation of these advances is given in the first, introductory chapter. |
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Page 299
... theory . Both minor and major chain rearrangements can be expected depending on the extent of chain entanglement . The fact that the entanglement structure retains a memory of the crosslinking procedure is a central tenet of the theory ...
... theory . Both minor and major chain rearrangements can be expected depending on the extent of chain entanglement . The fact that the entanglement structure retains a memory of the crosslinking procedure is a central tenet of the theory ...
Page 316
... theory . Although this study is far from complete , and in some instances incon- clusive , nothing has been found that outright invalidates the theory . However , some refinements and modifications of the theory may be necessary to ...
... theory . Although this study is far from complete , and in some instances incon- clusive , nothing has been found that outright invalidates the theory . However , some refinements and modifications of the theory may be necessary to ...
Page 438
... theory , 389-390 Flory - Erman model , 422 theory , 291 , 379 , 383 , 390 , 394 , 424 , 431 Flory - Huggins equation , 382 Flory - Rehner theory , 382 Fluorescence physics of , ' 398 polarization , 393-406 orientation , 399-401 ...
... theory , 389-390 Flory - Erman model , 422 theory , 291 , 379 , 383 , 390 , 394 , 424 , 431 Flory - Huggins equation , 382 Flory - Rehner theory , 382 Fluorescence physics of , ' 398 polarization , 393-406 orientation , 399-401 ...
Contents
Introduction to Synthesis of Elastomers | 1 |
Structure and Properties of Tire Rubbers Prepared | 17 |
Polymer and Chain End Structure in Anionic Diene | 37 |
Copyright | |
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affine anionic antioxidant behavior block polymers butadiene calculated catalyst CH₂ chain end CHDI Chem chemical crosslinking crystalline crystallites crystallization curing curves cyclohexane deformation density diene dynamic mechanical effect elasticity elongation end block entanglements equation equilibrium experimental fatigue fraction function glass transition temperature groups hard segment content hard segment length higher hydrogenated hydrosilylation increase initiator intramolecular reaction isoprene Macromolecules measurements melting temperature microstructure modulus molecular weight molecules monodisperse monomer observed obtained oligomers orientation P. J. Flory PDMS peak phantom network phase Phys polybutadiene polyether polyisoprene polymerization polystyrene polyurethane-ureas polyurethanes prepared prepolymer PTMO rubber sample scattering segment length distribution shown in Figure soft segment solvent spectra strain stress stress-strain structure styrene swollen synthesis Table theory thermal thermoplastic thermoplastic elastomers tion toluene triblock copolymer uniaxial values vinyl content vulcanizates