Solution Dynamics of Synthetic and Natural Polyelectrolytes |
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Page 11
... monomer number density . It is important to note when comparing the models that Witten and Pincus define concentration as the number den- sity of charges c / A , where A is the effective number of monomers between uncondensed charges ...
... monomer number density . It is important to note when comparing the models that Witten and Pincus define concentration as the number den- sity of charges c / A , where A is the effective number of monomers between uncondensed charges ...
Page 32
... number of monomers per chain and the number of effective charges per chain . Thus the average number density of uncondensed counterions is c / A , where c is the number density of monomers . The mobility of the free counterions μ is ...
... number of monomers per chain and the number of effective charges per chain . Thus the average number density of uncondensed counterions is c / A , where c is the number density of monomers . The mobility of the free counterions μ is ...
Page 39
... number of monomers per effective charge , A , was calculated for each concentration as shown in Figure 3.3 . For this calculation , only data at concentrations exceeding 10-4M was used in order to be certain that the solution is ...
... number of monomers per effective charge , A , was calculated for each concentration as shown in Figure 3.3 . For this calculation , only data at concentrations exceeding 10-4M was used in order to be certain that the solution is ...
Common terms and phrases
added salt adenosine albumin and y-globulins anti-inflammatory apparent viscosity Aspirin binding Bjerrum length BSA & globulins calculated chain length dependence Chapter Concentration dependence correlation length counterion condensation D)-penicillamine data for NaPAMS dependence of viscosity determined dielectric constant Dobrynin drugs effective charge electrostatic blob entangled solution entanglement concentration Equation experimental filled circles frequency function of shear Hyaluronan hyaluronic acid hydroxychloroquine ibuprofen interactions measured Methotrexate mg/mL NaHA molecular weight molecular weight samples NaPAMS Mw NaPAMS solutions NaPSS neutral polymers number of monomers open triangles osmotic pressure phosphate buffered saline polyelectrolyte chain polyelectrolyte solutions polyion polymer poor solvent regime Rheological data rheology Rinaudo scaling prediction scaling theories semidilute solution semidilute unentangled solution shear history shear rate Shear Rate s¹ shear thinning shown in Figure sodium hyaluronate specific conductance specific viscosity stainless steel Sulfasalazine synovial fluid model terminal modulus viscoelasticity viscosity data weak reversible gel Witten and Pincus