Carbon Based Magnetism: An Overview of the Magnetism of Metal Free Carbon-based Compounds and Materials

Front Cover
Tatiana Makarova, Fernando Palacio
Elsevier, Jan 16, 2006 - Science - 576 pages

Carbon Based Magnetism is the most complete, detailed, and accurate guide on the magnetism of carbon, the main element of living creatures. Written by the leading experts in the field, the book provides a comprehensive review of relevant experimental data and theoretical concepts related to the magnetism of metal-free carbon systems. These systems include carbon based compounds, namely organic radical magnetic systems, and magnetic materials based on carbon structures. The aim is to advance the understanding of the fundamental properties of carbon.

This volume discusses all major modern hypotheses on the physical nature of magnetic ordering in carbon systems. The first chapters deal with magnetic ordering mechanisms in p-electron systems as well as molecular magnets with spins residing only in p-orbitals. The following chapters explore the magnetic properties of pure carbon, with particular emphasis on nanosized carbon systems with closed boundary (fullerenes and nanotubes) and with open boundary (structures with edge-localized magnetic states). The remaining chapters focus on newer topics: experimental observation and theoretical models for magnetic ordering above room temperature in pure carbon. The book also includes twenty three review articles that summarize the most significant recent and ongoing exciting scientific developments and provide the explanation. It also highlights some problems that have yet to be solved and points out new avenues for research.

This book will appeal to physicists, chemists and biologists.

  • The most complete, detailed, and accurate Guide in the magnetism of carbon
  • Dynamically written by the leading experts
  • Deals with recent scientific highlights
  • Gathers together chemists and physicists, theoreticians and experimentalists
  • Unified treatment rather than a series of individually authored papers
  • Description of genuine organic molecular ferromagnets
  • Unique description of new carbon materials with Curie temperatures well above ambient.

From inside the book

Contents

Persistent Highspin Organic Polyradicals
53
Verdazylbased Magnetic Systems
75
Quantum Spin Magnetism in Nitroxidebased Compounds
107
The Magnetism of PiOrbitals under Pressure
131
Spin Density Distribution and Interaction Mechanisms in Thiazylbased Magnets
159
Magnetic Bistability in Moleculebased Magnetic Materials
189
The Nature of Effective Exchange Interaction
201
Magnetism of Fullerene Chargetransfer Complexes
229
Interactions and Disorder in 2D Graphite Sheets
353
The Magnetic Nature of Intrinsic and Irradiationinduced Defects in Carbon Systems
371
Unconventional Magnetic Properties of Nanographite
397
Ferromagnetic and Superconducting Instabilities in Graphite
417
Induced Magnetic Order by Ion Irradiation of Carbonbased Structures
437
Magnetic Properties of Novel Carbon Allotropes
463
McConnel Model for the Magnetism of Cgobased Polymers
483
The Mechanism of the Magnetic Interaction in PolymericC60 Fullerenes
501

Diamagnetism of Diamond and Graphite
245
Electronic and Magnetic Properties of Nanographites
279
Flatband Ferromagnetism in Organic Crystals
305
Magnetism in Nanometerscale Materials that Contain No Magnetic Elements
329
Ferromagnetism in Defective Polymerised C6o
523
Ferromagnetic Carbonaceous Compounds
541
index
563
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Page 282 - The energy difference between the top of the valence band and the bottom of the conduction band is called the band gap.
Page 129 - This work was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology of Japan. Part of this work was carried out at the Strategic Research Base "Handai Frontier Research Center" supported by the Japanese Government's Special Coordination Fund for Promoting Science and Technology.
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About the author (2006)

Tatiana Makarova’s research interests are in carbon-60 solids. In 2001, as a member of an international team from Sweden, Germany, Brazil and Russia she found a small ferromagnetic signal in a polymerized form of fullerene. This experiment proved to be the catalyst for the current interest in magnetic carbon.

Fernando Palacio is Professor of Research of the Consejo Superior de Investigaciones Científicas at the Instituto de Ciencia de Materiales de Aragón and member of the Condensed Matter Physics Department at the University of Zaragoza. His research interests are in molecular magnetism, the magnetism of disordered antiferromagnets and magnetic nanocomposites, where he has published over two hundred research articles and edited two books.

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