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The Chemical and Physical Structure of Polymeric Solids
Theories of the Limiting Moduli and the Static Dielectric
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acrylate activation energy amorphous polymers amorphous regions annealing atactic atoms behaviour bonds Chem copolymers crosslinked crystal crystalline crystalline polymers decrease degree of crystallinity density dielectric and mechanical dielectric constant dielectric loss dielectric relaxation dipole distribution effect Equation experimental Ferry Frohlich function given glass transition glass-rubber relaxation Heijboer Illers increasing Ishida isotactic Jenckel kcal/mole loss peak loss tangent magnitude main chain maximum loss McCrum measurements mechanical and dielectric mechanical relaxation methacrylate polymers methyl Mikhailov molecular weight motions nylon observed obtained occurs Phvs Phys plasticizer plots PMMA Polvmer Sci polyamides polydian carbonate polyethylene polymer chain Polymer Sci polymerization polymethyl methacrylate polypropylene polystyrene polyvinyl acetate PVAc PVOH relaxation region repeat unit resonance rotation rubber Saito sample Schmieder and Wolf shear modulus shown in Figure side-group single relaxation specimen spherulites stereoregularity stress relaxation studied syndiotactic Takayanagi Temperature dependence theory tion Willbourn Yamafuji