Anelastic and Dielectric Effects in Polymeric Solids |
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Page 27
... formed by the addition of unsaturated monomers to the growing chain without the elimination of water or other small molecules . Hence , condensation polymers comprise structural units which lack certain elements present in the monomers ...
... formed by the addition of unsaturated monomers to the growing chain without the elimination of water or other small molecules . Hence , condensation polymers comprise structural units which lack certain elements present in the monomers ...
Page 36
... formation of crosslinked networks in polymers may also have some effect on polymer properties . Diene monomers ... formed from viscous liquids or rubber - like materials which show ir- reverisible behavior ( e.g. permanent set ) to ...
... formation of crosslinked networks in polymers may also have some effect on polymer properties . Diene monomers ... formed from viscous liquids or rubber - like materials which show ir- reverisible behavior ( e.g. permanent set ) to ...
Page 172
... formed by the redistribution of free volume . They considered a model of a liquid consisting of hard spheres and assumed that no energy change was associated with the redistribution of free volume . For the self - diffusion coefficient ...
... formed by the redistribution of free volume . They considered a model of a liquid consisting of hard spheres and assumed that no energy change was associated with the redistribution of free volume . For the self - diffusion coefficient ...
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Anelastic and Dielectric Effects in Polymeric Solids N. G. McCrum,Bryan Eric Read,Graham Williams (Ph.D.) No preview available - 1967 |
Common terms and phrases
acrylate activation energy amorphous polymers amorphous regions annealing atactic atoms bonds Chem copolymers crosslinked crystal crystalline crystalline polymers curves decrease degree of crystallinity density dielectric constant dielectric loss dielectric relaxation dipole distribution dyn/cm² Equation experimental Ferry glass transition glass-rubber relaxation Heijboer Illers Illers and Breuer increasing Ishida isotactic kcal/mole Log f c/s loss peak loss tangent magnitude main chain maxima maximum loss McCrum measurements mechanical relaxation methacrylate polymers methyl Mikhailov molecular weight molecules motions observed obtained occurs Phys plasticizer plots PMMA polyamides polydian carbonate polyethylene polymer chain Polymer Sci polymerization polymethyl methacrylate polypropylene polystyrene polyvinyl acetate PVAc PVOH relaxation region repeat unit rotation rubber Saito sample Schmieder and Wolf shear modulus shown in Figure side-group single relaxation specimen spherulites ẞ peak ẞ process ẞ relaxation stereoregularity stress relaxation studied syndiotactic Takayanagi Temperature dependence theory tion Yamafuji