Molecular Basis of Polymer Networks: Proceedings of the 5th IFF-ILL Workshop, Jülich, Fed. Rep. of Germany, October 5–7, 1988Artur Baumgärtner, Claude E. Picot The workshop on the "Molecular Basis of Polymer Networks", held October 5- 7, 1988 in 1iilich, FRG, continued a series of workshops jointly organized by the Institute Laue Langevin (ILL) in Grenoble, and the Institute of Solid State Physics of the KFA, 1iilich. The aim of this workshop was to provide a platform for discussions between theoreticians and experimentalists interested in the physics of polymer networks, in the hope that the two types of discussion would be synergistic. As revealed by the title of this workshop, the main focus of the lectures was on molecular aspects of the problem. The individual parts of these proceedings cover various approaches. Following quite general comments from a physicist examining the situation from "outside", various new theoretical concepts are developed. During the last decade the advent of Small Angle Neutron Scattering (SANS) has allowed the molecular structure of polymer networks to be studied and thus the reliability of the theories to be tested directly at the molecular level. Recent advances in this field are presented. The use of new techniques such as 2H NMR or QELS and the refinements of more classical, mechanical experimental measure ments have provided new information about the relation between the macroscopic behavior and the microscopic structure of polymer networks. Some recent results in this area are discussed for both chemically cross-linked networks and gels built by specific interchain interactions. |
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Page 3
... macroscopic level do not appear . to Thus the macroscopic approach is also necessary and in general it leads non - trivial results which are easily found , even when the microscopic state of the system is perfectly known . To study the ...
... macroscopic level do not appear . to Thus the macroscopic approach is also necessary and in general it leads non - trivial results which are easily found , even when the microscopic state of the system is perfectly known . To study the ...
Page 52
... macroscopic deswelling ( see Fig . 5 ) . If the distance between any pair of points ( not only junctions ) along the chain changed affinely in the macroscopic deformation , the isotropic plateau shaped curve would simply be shifted ...
... macroscopic deswelling ( see Fig . 5 ) . If the distance between any pair of points ( not only junctions ) along the chain changed affinely in the macroscopic deformation , the isotropic plateau shaped curve would simply be shifted ...
Page 139
... macroscopic networks . Because of they are much easier to handle , and they can be their solubility characterized in solution . We wish to describe results which were obtained from two different classes of micronetworks : in The first ...
... macroscopic networks . Because of they are much easier to handle , and they can be their solubility characterized in solution . We wish to describe results which were obtained from two different classes of micronetworks : in The first ...
Contents
Remarks | 2 |
Statistical Mechanics of dDimensional Polymer Networks and Exact | 17 |
FluctuationInduced Deformation Dependence of the FloryHuggins | 35 |
Copyright | |
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42 Editors anisotropy Basis of Polymer Bastide Baumgärtner and C.E. behaviour C.E. Picot Molecular calculated carrageenan chain segments Chem chemical chemical potential conformation constraints corresponding crosslinking curves deformation density deswelling deuterated distribution dynamics effect elastic free energy elementary strand elongation entanglements equation equilibrium excluded volume experimental experiments exponent factor Flory Flory-Huggins Flory-Huggins theory fluctuations fractal dimension free chains free energy Gaussian gelation Heidelberg 1989 interaction parameter isotropic labelled paths length linear Macromolecules macroscopic melt modulus molecular weight monomers network chains Networks Springer-Verlag Berlin neutron scattering observed obtained P.G. de Gennes PDMS chains phantom network Phys Picot Molecular Basis polybutadiene polyelectrolyte Polymer Networks Springer-Verlag polymeric fractals Proceedings in Physics radius of gyration ratio relaxation sample scaling solution solvent Springer Proceedings star molecules structure swelling swollen temperature theory topological uniaxial values vector Vilgis viscoelastic viscosity volume fraction