Glass, Volume 22 |
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Page 50
From a thermodynamic view three mechanisms will be distinguished that can
play a predominent role and are often coupled : Processes that are driven by a
concentration - controlled difference of chemical potential ( diffusion processes ) .
From a thermodynamic view three mechanisms will be distinguished that can
play a predominent role and are often coupled : Processes that are driven by a
concentration - controlled difference of chemical potential ( diffusion processes ) .
Page 64
The chemical reactivity of a glass with given composition is influenced by the “
frozen - in ... Hench and Clark ( 1978 ) demonstrated a clear influence of the
chemical activity of alkali ions in the solution on the one hand and in the glasses
on the ...
The chemical reactivity of a glass with given composition is influenced by the “
frozen - in ... Hench and Clark ( 1978 ) demonstrated a clear influence of the
chemical activity of alkali ions in the solution on the one hand and in the glasses
on the ...
Page 223
An equation for the rate constant k of a chemical reaction is k = ko exp ( - AG * /
RT ) ( 56 ) where AG * is the free energy of activation and ko is weakly dependent
on temperature or pressure . If the pressure P is a variable as well as the ...
An equation for the rate constant k of a chemical reaction is k = ko exp ( - AG * /
RT ) ( 56 ) where AG * is the free energy of activation and ko is weakly dependent
on temperature or pressure . If the pressure P is a variable as well as the ...
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Contents
Water in Glass | 75 |
Applications | 121 |
Gel Method for Making Glass | 129 |
Copyright | |
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acid addition adsorption alkali alkoxide analysis applied atoms band Bartholomew bond bulk calculated cause Ceram Chem chemical clusters coefficient components composition concentration constant contraction crack crystals curve decrease dependence depth determination developed discussed distribution Doremus effect energy equation et al example expansion experimental failure fatigue fibers formation formed fracture function geometry give given glass surfaces groups heating higher hydrated hydrolysis hydrosilicate important increase influence ions Kamiya layer lead length load lower material mean measured melting metal method mole observed obtained occurs oxide phase Phys possible prepared pressure processes produced propagation properties range ratio reaction region samples seal shown in Fig shows silicate glasses SiO2 soda-lime Solids solution strain strength stress structure studies Table technique temperature thermal tion values vapor viscosity water content