Treatise on materials science and technology |
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Page 115
Epel'baum and Salova (1978) measured the molar volume of a series of Na20-
Si02 and Na20-Al203-Si02 glasses and found that the molar volume was a linear
function of the mole ratio of water to silicon, although for glasses with the Na20 to
...
Epel'baum and Salova (1978) measured the molar volume of a series of Na20-
Si02 and Na20-Al203-Si02 glasses and found that the molar volume was a linear
function of the mole ratio of water to silicon, although for glasses with the Na20 to
...
Page 133
The most important factor of these is the concentration of water, expressed by the
mole ratio rw = [water]/[metal alkoxides]. Ti(0R)4 is hydrolyzed into chainlike
polymers forrw s 1 (Boyd, 1951; Minami et al., 1955). Ti(0C2H5)4 forms infinitely
...
The most important factor of these is the concentration of water, expressed by the
mole ratio rw = [water]/[metal alkoxides]. Ti(0R)4 is hydrolyzed into chainlike
polymers forrw s 1 (Boyd, 1951; Minami et al., 1955). Ti(0C2H5)4 forms infinitely
...
Page 134
/-C3H7)4 is 2 g, amount of Si(OC2H5)4 is 17.54 g, amount of C2H5OH for
dilution of H20 and CH3COOH is 40 ml. c Mole ratio denotes the [H20]/[alkoxides
] mole ratio. that the product of hydrolysis in this solution is a chainlike polymer.
/-C3H7)4 is 2 g, amount of Si(OC2H5)4 is 17.54 g, amount of C2H5OH for
dilution of H20 and CH3COOH is 40 ml. c Mole ratio denotes the [H20]/[alkoxides
] mole ratio. that the product of hydrolysis in this solution is a chainlike polymer.
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acid activation energy adsorbed adsorption alkali alkali ions alkoxide alkoxide solution atoms autoclave band Bartholomew BK7 glass bond borosilicate borosilicate glass bulk calculated Ceram Chem chemical durability clusters coefficient components concentration crack propagation crack tip crystals curve decrease density dependence desorption diffusion Doremus Dunken effect electron energy equation etching experimental fibers film formation fracture Friedrich-Schiller-Univ function fused silica glass surfaces heating hydrated hydrolysis hydrosilicate hydroxyl increasing infrared isotherm Jena Kamiya layer leached material measured melting metal method mole molecular water molecules Moriya Nogami Non-Cryst nonbridging oxygens oxide phase separation Phys polished powders properties protons ratio reaction refractive index Sakka samples Scholze shown in Fig shows Si02 glass silane silicate glasses soda-lime glass Solids spectra static fatigue strain strength structure surface region technique temperature tensile stress tion ture values vapor velocity viscosity water content water in glass Wiederhorn
Bibliographic information
| Title | Treatise on materials science and technology Volume 22 of Glass, Minoru Tomozawa |
| Authors | Herbert Herman, Minoru Tomozawa |
| Editors | Herbert Herman, Minoru Tomozawa |
| Edition | illustrated |
| Publisher | Academic Press, 1982 |
| Original from | the University of Michigan |
| Digitized | 29 Nov 2007 |
| ISBN | 0123418224, 9780123418227 |
| Length | 320 pages |
| Subjects | › Glass Materials Research Technology & Engineering / Material Science |
| Export Citation | BiBTeX EndNote RefMan |