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acid activation energy adsorbed adsorption alkali alkali ions alkoxide alkoxide solution atoms autoclave band Bartholomew BK7 glass bond borosilicate borosilicate glass bulk calculated Ceram Chem chemical durability clusters coefficient components concentration crack propagation crack tip crystals curve decrease density dependence desorption diffusion Doremus Dunken effect electron energy equation etching experimental fibers film formation fracture Friedrich-Schiller-Univ function fused silica glass surfaces heating hydrated hydrolysis hydrosilicate hydroxyl increasing infrared isotherm Jena Kamiya layer leached material measured melting metal method mole molecular water molecules Moriya Nogami Non-Cryst nonbridging oxygens oxide phase separation Phys polished powders properties protons ratio reaction refractive index Sakka samples Scholze shown in Fig shows Si02 glass silane silicate glasses soda-lime glass Solids spectra static fatigue strain strength structure surface region technique temperature tensile stress tion ture values vapor velocity viscosity water content water in glass Wiederhorn