Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 88
... becomes ( μ'1 ) Po = ( 41 ) Po + Spo + * V1dP ( 8 ) The partial volume of water changes so little with pressure as to be negligible over any reasonable range of so that V1 may be placed out- side the integral sign for this purpose ...
... becomes ( μ'1 ) Po = ( 41 ) Po + Spo + * V1dP ( 8 ) The partial volume of water changes so little with pressure as to be negligible over any reasonable range of so that V1 may be placed out- side the integral sign for this purpose ...
Page 265
... becomes p / TM , as would be ex- pected , for under these circumstances the protons of the water molecules exchanging from the hydration sphere have all relaxed , so that the re- laxation rate in the bulk solution is determined directly ...
... becomes p / TM , as would be ex- pected , for under these circumstances the protons of the water molecules exchanging from the hydration sphere have all relaxed , so that the re- laxation rate in the bulk solution is determined directly ...
Page 436
... becomes too high ( say about a million ) , the scattering effect due to the sample itself is unavoid- able , and the measurement of ORD becomes very difficult , especially in the shorter wavelength regions . In such cases one is forced ...
... becomes too high ( say about a million ) , the scattering effect due to the sample itself is unavoid- able , and the measurement of ORD becomes very difficult , especially in the shorter wavelength regions . In such cases one is forced ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero