Physical Principles and Techniques of Protein Chemistry, Part 3Sydney J. Leach |
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Page 409
... calculated the CD of random oligo- peptides by summing dipeptide CD spectra . The dipeptide CD spectra were calculated from a Boltzmann distribution over the conformational energy map , the CD calculations for each ( 4,4 ) angle ( 10 ...
... calculated the CD of random oligo- peptides by summing dipeptide CD spectra . The dipeptide CD spectra were calculated from a Boltzmann distribution over the conformational energy map , the CD calculations for each ( 4,4 ) angle ( 10 ...
Page 527
... calculated . In spite of the fact that the calculated shapes and the experi- mental curves are qualitatively similar for the most part , a serious and as yet unexplained discrepancy is found in the wavelength positions of the extrema ...
... calculated . In spite of the fact that the calculated shapes and the experi- mental curves are qualitatively similar for the most part , a serious and as yet unexplained discrepancy is found in the wavelength positions of the extrema ...
Page 529
... calculated rotational strengths and CD curves of the appropriate model compounds with experimentally determined parameters for the a - helix , poly - L - proline I and II , and collagen . In each case the magnitude of R is found to ...
... calculated rotational strengths and CD curves of the appropriate model compounds with experimentally determined parameters for the a - helix , poly - L - proline I and II , and collagen . In each case the magnitude of R is found to ...
Contents
25 | 4 |
E The Isopotential Specific Volume | 10 |
Direct Volume Change | 22 |
Copyright | |
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a-helical a-helix absorption band acid angle B-structure Beychok Biochem Biochemistry Biol Blout c₂ calculated CD band CD spectrum Chem chromophore circular dichroism coefficient Cohn coil complex concentration conformation contribution Cotton effects creatine kinase cross-section denatured determined dipole Doty electron density ellipticity enzyme equation equilibrium exciton experimental factor Fasman function helical content helix intensity interaction kinase Kratky lysozyme magnetic measurements method Moffitt molecular weight molecule myoglobin negative negative band obtained optical activity ORD curve parameters partial specific volume particles peptide perturbation Phys Pilz plot polarized poly-L-proline polymer polypeptides positive procedure protein protein solution pulse Pysh radius of gyration random coil region residues rotational strength rotatory sample Schellman Section shape small-angle solvent spectra sphere studies subunits T₁ temperature theory Tinoco tion transition transition dipole moment tyrosine vector wavefunctions wavelength Woody X-ray zero